I added amsmath for \lessgtr but it also needed for substack. You may read more about this command in the amsmath documentation or in the mathmode paper.
As @tohecz pointed out, one may need some spacing correction by mathrel. Furthermore i added a vertical correction with the optional argument of \\. This makes the symbol a little bit more like belonging together (and might be a thing of personal taste too).
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I'd avoid such unclear symbology, to be honest.