For non-numerical content in S columns, you should generally enclose the content of the cells in braces ({}). In particular, siunitx uses the letter e for numbers with scientific notation, e.g. 2e3 for 2\times 10^3. This is the cause of the error you see. Hence, replace both cases of
Best Answer
The command
\si{units}
is for units only. You have to use the\SI{number}{units}
for what you want to do.