Quantum Mechanics – Three Particle Composite Angular Momentum States

angular momentumquantum mechanicsquantum-spin

I'm working on this problem to determine the ground state angular momenta ($S,L,J$) for nitrogen using Hund's rules, and I want to see if the total orbital angular momentum $L=2$ is possible (the states have to be antisymmetric). In this case, the three $2p$ electrons all have $l=1$.

To my understanding, if the "top of the ladder" ($L = M$) of the composite states with $L=2$ is symmetric/antisymmetric, then the whole collection of states with $L=2$ is symmetric/antisymmetric. Hence, we can examine the composite state $|22\rangle$.

I am unable to find a Clebsch-Gordan table for 3 particles, so I just added up the first two electrons, and then added the third to the composite state of the two.

Since the third electron has $l=1$, the composite state of the first two electrons can have either $L_{12}=1$ or $L_{12}=2$ in order to obtain that final $L=2$. With reference to the Clebsch-Gordan table, if $L_{12} = 1$, then
$$
|22\rangle = |11\rangle_{12}|11\rangle_3 = \frac1{\sqrt 2}(|11\rangle_1 |10\rangle_2 – |10\rangle_1 |11\rangle_2 )|11\rangle_3,
$$

and if $L_{12} = 2$, then
$$
|22\rangle = \sqrt{\frac23}|22\rangle_{12}|10 \rangle_3 – \sqrt{\frac13}|21\rangle_{12}|11 \rangle_3 = \sqrt{\frac23}|11\rangle_1|11\rangle_2|10 \rangle_3 – \sqrt{\frac13}\sqrt{\frac12}(|11\rangle_1 |10\rangle_2 + |10\rangle_1 |11\rangle_2)|11\rangle_3.
$$

I noticed that not only are these states not antisymmetric, they are not even symmetric, meaning that if I put the three electrons in the $|22\rangle$ state, exchanging two of the electrons will change the wave function. How could that be if electrons are identical? Otherwise, what went wrong with my procedure, and what is the proper way of adding the angular momenta of three particles?

Best Answer

your calculations are correct, however your beginning assumption is not: the $L=2$ states do not have do be specifically symmetric or antisymmetric. Looking at the representation $1\otimes 1 \otimes 1 =(2\oplus 1 \oplus 0)\otimes 1 = 3\oplus 2\cdot2 \oplus 3\cdot1 \oplus 0$, you can see that you can form $2$ representations of $L=2$. This hints that combined, at each value of $L_z$, the $2$ dimensional space is a standard representation of $S_3$. This is why the two states you calculated in the case $L_z=2$ are not symmetric.

In order to get the correct fully antisymmetric wave function of the three electrons, you need to combine these states with the $s=1$ states of spin (if you're familiar with particle physics, this is a bit how you combine the wave functions of the quarks to get the spin 1/2 baryons like the nucleons).

For the final resolution of your problem, I would recommend using different states though. Setting $|L_{z1}L_{z2}L_{z3}\rangle_o$ the orbital angular momentum states (no ambiguity since $L_1=L_2=L_3=1$) and similarily $|s_{z1}s_{z2}s_{z3}\rangle_s$ for the spin part (no ambiguity since $s_1=s_2=s_3=1/2$), it is usually more simple to consider: $$ |(12)\rangle_o = \frac{1}{\sqrt 2}(|101\rangle_o-|011\rangle_o) $$ $$ |(23)\rangle_o = \frac{1}{\sqrt 2}(|110\rangle_o-|101\rangle_o) $$ $$ |(31)\rangle_o = \frac{1}{\sqrt 2}(|011\rangle_o-|110\rangle_o) $$ which are linear combinations of the two states you identified in the $L=L_z=2$ subspace. They may not be orthogonal and independent, but they make the symmetrisation process more transparent.

Hope this helps and please tell me if you find some mistakes.