[Physics] Why is the voltage of a battery equal to the emf

batteriescoulombs-lawelectric-circuitselectricityvoltage

We know that there is an electric field inside the battery that works against the moving electrons of a circuit. But there is also the chemical force of the battery that at some point become equal. Voltage drop is the integral of the electric field over a closed loop. But you must also have the same integral over the same loop for the chemical force field. EMF is called precisely that, the integral of the chemical force field over a closed loop(the loop with the battery inside). So, can you give me an answer to "Why is the voltage of a battery equal to the EMF?" and having the forces and the integrals in your explanation?
Where does the integral of the electric field go? I might be missing or misunderstanding some very basic things about work and voltage, so excuse me if this is the case!

Best Answer

Imagine a free-standing battery (not connected to any wires) and take a closed loop through the battery, out one terminal, and back in the other terminal. The total work done in moving a test charge around that loop must vanish. For this to happen, the change in electric potential outside of the battery must equal the negative of the EMF change within the battery. $$\int_\mathrm{outside}\vec{E}\cdot{\mathrm{d} \vec{\ell}} + \mathcal{E} = 0$$

Update after comments

Work is well defined as the integral of force over distance. The relationship between work and energy is more subtle. One needs to carefully define what the system in question is. We also have to recognize that potential energy is the energy associated with the configuration of a system of interacting entities. One is on thin ice if one refers to "the potential energy of a particle". Particles do not have potential energy. The system comprising the particle and something with which it interacts has potential energy. (A ball does not have potential energy. The earth-ball system has potential energy.) I'll review the background on this, with apologies if the background is already well-understood.

Once a system is defined, energy can be added to the system by an external force which can do external work on the system. Work is one way energy can be added. Heat is another, but we'll mostly ignore heat and thermal energy. Generally, $$W_\mathrm{external} = \Delta E$$ where $E$ is the total energy of the system. External work causes energy to be added to the system, but once inside that energy could be potential, kinetic, thermal, chemical ...

Potential energy is defined to be the negative of the work done by forces internal to the system:$$W_\mathrm{internal} = -\Delta PE$$

Now our system. Let's take it to be the wire, the battery terminal, the conductors inside the battery, but not the chemicals and processes that generate the "chemical force". The chemical processes are a source of energy, so we'll take it to be outside of our system. The work done by the chemical processes are external, and do external work on the charge carriers $$W_\mathrm{external}=q\mathcal{E}$$ But the internal voltage due to the separated charges within the battery, also do work, but this work is internal to our system, and thus changes the potential energy of the system $$W_\mathrm{interal} = -\Delta PE = -qV$$ but recall $$W_\mathrm{external} = \Delta E = \Delta PE = -W_\mathrm{internal}$$ (ignoring stores of energy other than potential energy within the system). Finally $$q\mathcal{E}=qV$$ $$\mathcal{E} = V$$

Related Question