everyday-lifefluid dynamics
When driving a car while smoking with the window open (safety and legal issues aside), I've noticed that the smoke tends to go outside the window.
Bernoulli's equation is frame-dependent as the following paper shows it in a nice way
The Bernoulli equation in a moving reference frame
The essence of the argument is to realize that in a frame where the obstacles, around which the fluid moves, are not stationary, these surfaces do non-zero work. And one must account for this work done when using the Bernoulli equation.
A better way is to look at the generalized Bernoulli equation as done here, which also covers viscous fluids.
Your car is perfect for the generation of turbulence by flow separation. Behind the car, the flow cannot follow the car contours. You get circulation patterns on many scales (i.e. a lot of large and small turbulent structures). Naturally, there will be pressure differences at the opening. Consequently, there will be an exchange between outer and inner air. The exhaust gases are being circulated upwards around the rear of the car and become part of this exchange. If there is a mean inflow through the lower part of the opening, there will be a circulation within the car and the whole cargo space will be filled with exhaust gas in no time.
Here is an illustration of the turbulent flow around a car:
Best Answer
It is called Venturi Effect.
The increase in speed of the air surrounding your vehicle comes with a decrease in pressure. That explains too why a chimney works better in windy days.
The Venturi effect is explained by applying the Bernoulli Equation (say, the conservation of energy of a small piece of fluid that moves within the flow) between two points along a streamline (in this case, we would follow a piece of air in a tunnel wind)
$\frac{1}{2} \rho v^2 + \rho g h + p = \text{constant}$
The increase in the first summand when the flow gains speed to adapt itself to the shape of the car, is compensated by a decrease in the pressure $p$. Look what happens in this picture (wikipedia) when the flow changes speed to adapt to the shape of the tube:
(Image from wikipedia) $ $
Note the similarity with the high school equation for the conservation of mechanical energy of a particle:
$\frac{1}{2} m v^2 + m g h = \text{constant}$
(Just change the mass of the particle for the mass of a fluid volume unit, i.e. density, and add an additional summand to accout for the pressure, and you have Bernouilli's equation)
Bernouilli's equation is meant for an incompressible flow (water) which here means that the numerical results would be approximate, but qualitatively the same effect happens.
A related, interesting fact, is that submarine propellers must be carefully designed, in order to avoid points in which water suffers much too rapid a speed increase. When that happens, pressure becomes so low in that points that vacuum bubbles appear. The power released by the implosion of that bubbles against the surface of the propeller, not only is noisy, but also may damage the propeller itself. The phenomenon is called cavitation.
(Image from wikipedia)