[Physics] Why does fluid compression cool it up, unlike solids

condensationpressuresolid mechanicsthermodynamicswater

Why is it that solids on compression [As in striking a hammer etc.] heat up,
but liquids and gases on compression [Pressurizing liquids causes them to freeze or gases to liquify] cool down?

Best Answer

Your basic premise is wrong. Compressing things makes them heat up. With gasses this is even nicely predictable over a wide range. Look up something called the ideal gas law.

If you compress a gas enough then it will undergo a phase change and turn to liquid. This will release even more heat than just compressing the gas because the gaseous state of a substance has more energy than the liquid state. This is what the heat of vaporization is about, and why you have to heat a liquid to make it boil (change phase to its gaseous state).

Steam heat systems work on the reverse principle. The steam condenses on the inside of the pipe, thereby releasing a lot of heat, which heats the pipe, which heats the room. The condensed water returning to the boiler contains less energy than when it left the boiler as steam.