[Physics] Why does an atom in an oscillating electric field behave like an electric dipole

atomic-physicsdipoleelectric-fieldsquantum mechanics

How can I understand that an atom subjected to an oscillating electric field (e.g., $\vec{E}=\hat{i} E_0\cos\omega t$) behaves like an oscillating electric dipole? What is the underlying picture that comes out of the quantum mechanical description of the atom?

Best Answer

Well, let’s start with a static electric field: the electrons would move in the opposite direction of it and the nucleus in the same direction. But the nucleus’ and the electrons’ attractive force counteracts this process, thus forming a (steady) dipole. I know, the picture I painted is very classical, but that’s sufficient. To solve it quantum mechanically you would have to use perturbation theory, only to find the same result. Now if the external electric field oscillates, the dipole will oscillate accordingly.

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