[Physics] Why do some protons align against the magnetic field

nuclear-magnetic-resonancequantum-spin

I was learning about proton NMR (Nuclear Magnetic Resonance Spectroscopy) which is where protons (with their own spins) are subjected to an external magnetic field and a radio frequency is applied to flip their spin states and the re-emitted frequencies are measured.

What I don't understand is why do some protons decide to align their spins against the magnetic field [Figure 2 – some are pointing the wrong way]. This seems ridiculous atleast from the everyday experience of compasses (a compass needle always points to North).
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I guess it seems weird that something would naturally assume a higher energy state. I would appreciate an explanation as to why they don't all point in the direction of the magnetic field.

Best Answer

The protons are not isolated but they are inside a material with a non-zero temperature. The thermal motion will provide the energy for the protons to be excited in a state with higher energy, corresponding to the alignment opposite to the field. This is a dynamic process, after some the times they go back to the ground state but other protons are excited all the time. For a specific temperature, there is an average fraction of protons aligned in the opposite direction. The same mechanism explains why the magnetization of a piece of iron in a magnetic field depends on temperature or how the magnetization of a paramagnetic material depends on temperature. See for example this typical curve of magnetization versus temperature: http://www.irm.umn.edu/hg2m/hg2m_b/Image9.gif

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