[Physics] Why are most ferromagnets metals while antiferromagnets are insulators

condensed-matterelectromagnetismsolid-state-physics

This seems to be experimentally true, but I don't quite have an intuition as to why. In the Ising model, we usually consider an insulating ferromagnet if $J>0$, where $J$ is the exchange coupling. Does this situation not usually occur in reality?

Best Answer

First let me make two comments before answering the question.

  1. The difference between metal and insulator rest in the existence of the itinerant electron Fermi surface or not. Ising (or Heisenberg) model is just an effective theory of local moments (localized electrons in the atoms), which contains no information of the itinerant electron, so there is no hope to start from an Ising model and explain the difference between metal and insulator.

  2. The observation that "ferromagnets are mostly metals, while antiferromagnets are mostly insulators" is not quite true. There are ferromagnetic insulators like $\text{Fe}_3\text{O}_4$, which is one of the earliest ferromagnets discovered in human history. There are also examples of antiferromagnetic metals, from the historical ones like $\text{Cr}$ to the most recent ones like the parent compounds of iron-base superconductors (e.g. $\text{Ba}\text{Fe}_2\text{As}_2$).

The different magnets arise from the different magnetic exchange mechanisms in the material. In the following, some most famous exchange mechanisms in the solid are listed, but as the material can be complicated, so the list is far from complete.

  • Ferromagnetic metal: itinerant exchange (RKKY interaction),
  • Ferromagnetic insulator: double exchange,
  • Antiferromagnetic metal: Fermi suface nesting and SDW instability,
  • Antiferromagnetic insulator: superexchange.

In many transition metals (e.g. $\text{Fe}$), the exchange interaction between magnetic ions are mediated by the itinerant (conduction) electrons. The transition metal system contains both the itinerant electrons and the local moments (typically from $d$ orbitals). Local moments just sit on each atom while the itinerant electron travels between the atoms. When the itinerant electron meets the local moment, they mutually polarize each other towards the same orientation. So as the itinerant electrons travel between the atoms, the message of the magnetic orientation is brought from one local moment to another. So eventually all local moments tends to align in the same direction with the itinerant electron, and as the local moment orders, more itinerant electron will be polarized to the ordering orientation to reinforce the ordering. Therefore the ferromagnetism is developed in the metal by this collective behavior. This mechanism is known as the itinerant exchange or the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction. In the real space, the RKKY interaction between two local moments of the distant $r$ follows the oscillatory behavior $$J_\text{RKKY}(r)\sim-\frac{\cos(k_F r)}{r^3}.$$ As in the dilute limit $k_F r\ll 1$ for many metals, ferromagnetism will dominate.

Antiferromagetic insulators are usually Mott insulators, in which the Fermi surface is gapped out by interaction, and there is no itinerant electrons. In this case, the magnetic correlation must be mediated by another mechanism, which is known as the superexchange. In the simplest Mott insulator (e.g. $\text{Mn}\text{O}$), each magnetic ion $\text{Mn}^{2+}$ would have a single unpaired electron in a $d$ orbital, which can hop between $\text{Mn}$ sites as bridged by the $\text{O}^{2-}$ ion in between. When the electron spins on $\text{Mn}$ are opposite aligned, it can hybridize over the Mn-O-Mn unit and gain kinetic energy.

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However if the electron spins on $\text{Mn}$ are ferromagneitcally aligned, such hybridization will be forbidden by the Pauli exclusion principle. Therefore superexchange favors antiferromagnetism, and the effective exchange interaction is given by $J\sim t^2/U$ where $t$ is the effective hoping integral between $\text{Mn}$ sites, and $U$ is the on-site Coulomb repulsion.

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