[Physics] What makes an electron jump down to lower energy level

electronsenergyphotons

While I can easily grasp the mechanism of energy absorption by the atom system resulting in a jump of the electron to a higher energy level, i.e. receiving energy from the outside in the form of a photon, I cannot really understand why would an electron be interested, or be compelled to go back to lowest energy level available resulting in the emission of a photon ?!?
Which mechanisms are behind the scene for this to happen?
I came across a lot of explanations stating that "that's just the way electron like to be" :/
It's like saying that rain falls back down because water at the like to go back to the oceans.
Many thanks

Best Answer

You are asking about electron de-exitation, and there are basically two main types of processes involved, in any case, the electron/atom system moves to a lower energy level if there is such a lower energy level available:

  1. spontaneous emission:

In this case the excited atom/electron system transitions to a lower energy level, while emitting a photon. This form of emission is mainly a QM phenomenon, and you are asking why it happens. In this case, the answer is quantum mechanics itself, a trigger for the process can only be understood with the explanations in QED and vacuum fluctuations.

Spontaneous emission in free space depends upon vacuum fluctuations to get started.[7][8]

https://en.wikipedia.org/wiki/Spontaneous_emission

  1. stimulated emission

In this case, an incoming photon of a specific frequency can interact with the electron/atom system, and cause it to transfer to a lower energy level.

The liberated energy transfers to the electromagnetic field, creating a new photon with a phase, frequency, polarization, and direction of travel that are all identical to the photons of the incident wave. This is in contrast to spontaneous emission, which occurs at random intervals without regard to the ambient electromagnetic field.

https://en.wikipedia.org/wiki/Stimulated_emission

It is very important to understand that I mentioned everywhere a photon emission but there are mainly two types of such processes, radiative and non-radiative transitions. In the case of the latter no photon is emitted.

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Just a note, there are other forms of transitions, like fine and hyperfine transitions too.