[Physics] What keeps water molecules in air from falling down

evaporationstates-of-matter

I was thinking about evaporative cooling, how the particles in water with the most velocity fly out of the water, leaving it colder. But then I thought, how come these water molecules stay in the air without falling back down to the liquid? Which begs the question, how do any water molecules in air stay in it?

I mean, they are heavier than air. Gravitation works on them just fine, so without air in the way they would certainly fall straight down with the same velocity of any human-sized falling object. So I would guess that the air molecules in the way between them and the floor are keeping them up. But how can they do it? I assume that air molecules are keeping each other up from the ground because they have a bigger force between them (in room temperature) than water molecules do, because air is gas in room temperature. But water isn't gas in room temperature so it shouldn't have such big repulsion forces between molecules. Or maybe I'm confused? Please shed light on this.

Best Answer

I mean, they are heavier than air.

No.

Water is $H_2O$ which has a molecular weight of 18.

Nitrogen is $N_2$ which has a molecular weight of 28.

Oxygen is $O_2$ which has a molecular weight of 32.

Argon is $Ar$ which has an atom weight of 40.

So a water molecule has a mass that is less than that of all the significant components of air.

But then I thought, how come these water molecules stay in the air without falling back down to the liquid?

There is a dynamic equillibrium. When there is a body of water, with air containing water vapor above it, gas phase water molecules DO continuously condense into the liquid water. One way to verify this is to leave a $D_2O$ bottle exposed to the air for a period of time, and look at its proton NMR spectrum before and after.

In other words, if the liquid water is in equillibrium with moist air, the rate at which liquid water molecules enter the gas phase is equal to the rate at which gas water molecules enter the liquid phase. If the system is out of equillibrium, net evaporation or net condensation occurs, until equillibrium is reached.