[Physics] What causes molecules to vibrate when exposed to electromagnetic radiation

atomselectromagnetismphotons

TL;DR: why atoms gain kinetic energy when hit by a photon?

I'm trying to understand the process that converts light into heat. I found poor explanation that do not include the whole process.

  1. A photon hits an atom of a molecule
  2. The electron is excited and moved to a higher energy state
  3. Assuming the energy is not remitted
  4. The overall charge of the atom did not change (?)
  5. (?) causes the molecules to vibrate

Are the vibration caused by the change in charge between the molecules?

I assume that the atoms are not ionized, since it would cause the matter to conduct electricity, wouldn't it?

Am I missing something?

Best Answer

Even though photons have zero rest mass, they carry a finite amount of energy and momentum.

A photon's energy & momentum is given by,

$$E = h\nu\space,\space \space p = \frac{hc}{\lambda}$$ where $\nu$ and $\lambda$ are frequency and wavelength of the photon respectively.

If the photon is absorbed by an atom and not re-emitted, the energy of the photon is completely transferred to the atom. These kind of collisions are inelastic. The atom takes up the energy as kinetic or vibrational energy.

If a new photon is emitted immediately after photon absorption with the same energy as that of the incident photon, the overall collision is said to be elastic. There won't be a change in energy, however, changing momentum is allowed.

However, sometimes, the emitted photon doesn't necessarily have the same energy as that of the incident photon and this kind of collusion (overall process)is also called inelastic collision.(Raman Scattering & Compton Scattering)

This missing energy is taken up by the atom as kinetic energy or vibrational energy.

The answer is highly simplified. The energy gained from the photon could be used for other purposes such as pair production of particles, knocking electrons off, etc. Also, the mechanism of absorption and emission are a bit complicated.

References: Photon-Atom Interactions - MIT OCW