[Physics] Total orbital and spin angular momentum for a closed shell

angular momentumatomic-physicsquantum mechanics

I read one Phys.SE question similar to mine, in
Total angular momentum in a full shell
but the question was so confusing and vague. The answer, though, was helpful for me to understand a part of my question.
It's said that the total orbital and spin angular momentum for a closed shell is zero. I understand, as explained in the link above, that paired electrons in a closed shell have zero net spin. That's because each pair has one up electron and one down. But I can't realize why this holds for total orbital angular momentum too.

Best Answer

The total angular momentum of a closed shell is zero because for fixed $l$, we have the possible states labeled by eigenvalues of $L_i$ as $m_{l,i} = l,\dots,0,\dots,-l$ in integer steps. The sum over all $m_l$ inside a shell is always zero, so total angular momentum of a shell is zero.

This is just the generalization of the argument with "up/down" for spin, which is the case $l = \frac{1}{2}$.