[Physics] the temperature (and pressure) of the oxygen inside an oxygen bottle

pressuretemperaturethermodynamics

In the hospital or in a lab, one can see the huge oxygen bottles. A question is, what is the temperature of the oxygen inside the bottle? And what is the pressure inside?

We know the critical temperature of oxygen is far below the room temperature. Therefore, if the temperature is room temperature, the oxygen is in a gaseous phase. Since the density is high, the pressure must be very high.

If the temperature is below the critical temperature, then why does not it equilibrate with the environment?

Best Answer

The answer depends on the nature of the "huge oxygen bottles"...

You often see large ( around two stories high) tanks outside a hospital. They are distinguished by the name of the chemical firm, Union Carbide or Linde among others, painted on the side, and by the thick layer of frost found on the attached plumbing.

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These tanks hold liquid oxygen at low pressure (a few atmospheres at most) and very low temperature with very effective(but cheap) insulation. The low amount of inward heat flow causes some liquid oxygen to vaporize, raising the internal pressure. The tank isn't very structurally strong, so the generated pressure is relieved by usage in the facility, or by a pressure relief valve, which of course wastes oxygen. In extreme cases, a heater may be used to raise the internal pressure to meet the needs of the facility. Failure of this pressure relief valve (closed) is a major danger for this type of tank.

The other type of oxygen tank is the much smaller (maybe 6 feet by 12 inch diameter) steel tank.

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This is a very strong steel tank containing compressed oxygen gas at ambient temperature and very high pressure. The tank is heavy, expensive, and must be treated with great care. (I wouldn't use the set up in this photo; too tippy!) A complex pressure reducing valve is needed to give a controlled low pressure flow, If you examine such a tank (in a lab, for example), you may find a series of date stamps, possibly covering decades, on which the tank has been tested at some huge overpressure.

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Note: image edited to eliminate problematic stamp on tank...

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