[Physics] The significance of kelvin as a unit of absolute temperature

si-unitstemperaturethermodynamicsunits

$$PV=nRT$$

Where $P$ is pressure in pascals ($\text{Pa}$)
$V$ is volume in cubic metres ($\text{m}^3$)
$n$ is amount of substance in moles ($\text{mol}$)
$R$ is the gas constant having units, joules per mole kelvin
($\text {J K}^{-1}\text{ mol}^{-1}$)
$T$ is the temperature in kelvins ($\text K$)

The melting and boiling points of pure water are $0\ ^\circ\text C $ and $100\ ^\circ\text C $ respectively. $1\ ^\circ\text C$ is $\dfrac 1 {100}^\text{th}$ of the difference in temperature.

1 kelvin and 1 degree Celsius represent the same difference in temperature.

However, why is it that in any formula (such as the one above) involving temperature (not temperature difference), plugging in values will result in a nice and correct temperature?

For example, $P=100\ \mathrm{}$, $V=8.314\ \mathrm{}$, $n=1\ \mathrm{}$, $R=8.314\ \mathrm{\ \ }$
Plugging in the values will result in $T=100\ $
$100$ kelvin.

But what is the significance of 100 kelvin? Why could it not have been any other unit in an absolute temperature scale? e.g. 100 degrees Rankine

In simple formulas such as

$$\text{Displacement = Velocity} \times \text{Time}$$
I can understand that metres would be obtained when metres per second is multiplied with seconds. It does not make sense to obtain inches from the multiplication between metres per second and seconds.

Best Answer

You do not need to use the kelvins for the ideal gas formula. The important thing to know is that $PV \propto nT$ where $T$ is the absolute temperature and can be expressed in any arbitrary linear scale (as long as the temperature is still absolute), including the kelvin and the rankine scale.

However, if you choose the constant of proportionality to be $R$ given in J/(K mol), then the temperature's units must be in kelvins for the equation to make sense. But you're not forced to use such a constant. You could pick up any other constant and you could adjust the temperature scale you're using. In particular you could have picked the constant that would make the temperature in rankine units.

Edit: Since the title of the question refers to "formulas", let me mention a case I've seen up to several papers. With regard to thermoelectric materials, there is a $ZT$ factor that's used to gauge the quality of the material to be used as a thermoelectric one, for example to make a thermoelectric generator. The important thing is that $T$ must be the absolute temperature. Unfortunately many papers mention that $T$ is given in kelvins, while it is not necessarily the case. Fortunately enough, I would say most (good) papers refer to $T$ as being the absolute temperature and do not mention the units.

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