[Physics] the difference between Rayleigh scattering and Thomson scattering

electromagnetismquantum mechanicsscattering

After reading the wiki articles I know, that both Rayleigh scattering and Thomson scattering are elastic processes. But what is the essential difference between those two processes, their cross sections and energy dependence?

Best Answer

Rayleigh scattering is scattering from polarizable entities. The incident light induces a dipole moment, which re-radiates. Thomson scattering is scattering from free unbound charged "unpolarizable" particles.

The cross section for Rayleigh scattering decreases with the fourth power of wavelength. That for Thomson scattering is independent of wavelength.

Comparing their relative cross sections is tricky, because Rayleigh scattering depends on the size of the particle, the wavelength of light, and the polarizability of the particle, all of which can vary significantly. Thomson scattering has none of that.

The Wikipedia pages you cite have a few examples. Air in visible light has a Rayleigh cross section on the order of $10^{-31}\, \mathrm{m}^2$, and the Thomson cross section for an electron is on the order of $10^{-28}\, \mathrm{m}^2$

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