Temperature – The Definition of 1 Kelvin Explained

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1 K is defined as (1/273.15)th of the temperature of the triple point of water. At least, that's how it's defined in my book. But which scale is the triple point of water being measured in?

Celsius? Fahrenheit?

Best Answer

To answer this question it may help to take an example from a more familiar area of physics, and then discuss temperature.

For a long time the kilogram (the SI unit of mass) was defined as the mass of a certain object kept in a vault in Paris. Then the gram can be defined as one thousandth of the mass of that object, and so on. If you now ask, what units are being used to state the mass of the chosen object? then it does not matter as long as they are proportional to the scale of units you want to adopt. So if someone were to tell you the mass of the special object in pounds (e.g. 2.2 pounds) then you would still know that one gram is a thousandth of that.

With temperature it goes similarly. There is a certain state of water, water vapour and ice all in mutual equilibrium. That state has a temperature independent of other details such as volume, as long as the substances are pure and they are not crushed up too small. So that state has a certain temperature. It has one unit of temperature in "triple point units" (a temperature scale that I just invented). When we say the Kelvin is a certain fraction of that temperature, we are saying that a thermometer whose indications are proportional to absolute temperature must be calibrated so as to register 273.16 when it is put into equilibrium with water at the triple point, if we wish the thermometer to read in kelvin. For example, if the thermometer is based on a constant-volume ideal gas then one should make the conversion factor from pressure in the gas to indicated temperature be a number which ensures the indicated temperature is 273.16 at the triple point. You then know that your gas thermometer is giving readings in kelvin, and you never needed to know any other units. (Note, such a thermometer is very accurate over a wide range of temperature, but it cannot be used below temperatures of a few kelvin. To get to the low temperature region you would need other types of thermometer. In principle they can all be calibrated to agree where their ranges overlap.)

(Thanks to Pieter for a detail which is signaled in the comments and now corrected in the text, but I hope the comment will remain.)