[Physics] Specific heat capacity and temperature, 0 K

kinetic-theoryquantum mechanicstemperaturethermodynamics

I've found similar threads like this, but with no clear answer. I understand that the specific heat capacity of a substance increases with temperature, because the vibrational nodes and rotational movements of the atoms are quantized (I assume that the increase is because the energy is distributed evenly over all degrees of freedom?).

What I don't understand is why the heat capacity goes to zero as temperature goes to zero. This comes out of the mathematics, sure – but what is the physical explanation here? If the translational movements are not quantized (or temperature-dependent, rather), what is explanation?

I hope my question makes sense.

Best Answer

Short answer: at absolute zero there is one - and only one - energy state available to each particle. Any attempt to change the state of even a single particle introduces energy into the system and you're no longer at absolute zero. Put another way: if there were two energy states allowed for a particle, the number of available energy states would be N for N particles (any one of them might be in the second state), and the temperature, which is proportional to the logarithm of the number of available states, is greater than zero.