I got a question concerning the band strucutre of solids.
The reference I'm using is the book on solid state physics by Ashcroft/Mermin.
My problem is that I don't completely understand the reason why there exists a
band-index n. On the one hand Ashcroft gives a quite plausible explanation
saying that the general solution of the given eigenvalue problem H $\psi_k(r)$ = $E_{k}$ $\psi_k(r)$ can be decomposed into $\psi_k(r) = e^{i*k*r} u_{k}(r)$. Plugging this ansatz
into the Schroedinger-equation and applying H to the $e^{i*k*r}$ first we
obtain a new Hamiltonian $H_{k}$ that depends on the "wavevector" k and a
new eigenvalue-problem $H_{k} u_{k}(r) = E_{k} u_{k}(r)$. Now we fix k. The operator
$H_{k}$ acts on r and therefor produces a certain number of solution u_{n,k}(r).
These solution can be counted using the index n.
So far so good.
Then Ashcroft states that the second proof of Bloch's theorem shows that
$u_{k}(r)=\sum_{G} c_{k-G} e^{i G r}$. The sum is taken over all reciprocal lattice vectors G. He says that from this way of writing the function $u_{k}$ it is obvious that multiple solution do exists. I don't really understand why that is the case.
First i thought that you may think of the n-th solution to be $u_{k,n}(r)=c_{k-G_{n}} e^{i G_{n} r}$ where $G_{n}$ denotes the n-th reciprocal lattice vector.
However this doesn't seem plausible to me, since you need to have the sum to
proof that $\psi_{k}$ = $\psi_{k+G}$ and therefor E(k)=E(k+G).
As you can see I'm quite confused about all this. Actually I'm also a bit confused why
the reduction to the first brillpuin zone doesn't produce more than one Energy value for a given k.
Anyway, I'd be more than happy if someone could help me.
Thanks in advance!!
See you.
Best Answer
Ashcroft and Mermin are occasionally not too careful about notation, and so the resolution is, as Marek mentioned in a comment, related to the fact that $$ u_k = \sum_G c_{k-G}e^{iGr} $$ admits several solutions -- every set of coefficients $\{c\}$ corresponds to some function $u_k$, but we're only interested in the $n$ solutions that solve the Schroedinger equation.
Every delocalized band arises because of the hybridization of quantum states between unit cells. If there are $n$ states that the electron can occupy, their will be $n$ (possibly degenerate, depending on the symmetry of the $G$-space point) bands. I say this to clarify that there is no sense in which the band index corresponds to the set reciprocal lattice vectors.
However, to answer your last question, you're absolutely right that reduction to the first Brillouin zone does give you multiple values of $E$ for a given $k \in IBZ$. If I remember correctly A&M introduce band theory by starting with the nearly free electron model and should show explicitly that this is the case. In the tight binding picture (sometimes called Linear Combination of Atomic Orbitals) the energies for $k$ outside the IBZ fall back onto their values in the IBZ.
Continued:
Specifically, I wanted to point out that $E_n(k)=E(k+G_n)$ simply doesn't make any sense. Where did you read that? However the point is that the eigenvalues that make up a particular band are periodic in $G$, so it is true that $E_n(k)=E_n(k+G)$. Now, what this means is that a description with any more than the first Brillouin zone is redundant. The fact that you have multiple bands does not come from the reduction, though it can look that way at first, as A&M present it. I suggest skipping ahead to the chapter on tight binding to understand how multiple bands arise.
Continued again:
Okay, I didn't address this as clearly as I'd hoped. The reason a new quantum number appears at all is that we know from experience that $E(k)$ is not single-valued. The reason for this is that each atom has a set of discrete orbitals, and mathematically we can describe the motion of an electron in a lattice as tunnelings between these orbitals... However, these orbitals have very different symmetries, and we can not, for example, hop from an s-orbital on site-1 to a p-orbital on site-2. Thus each flavor of orbital symmetry will basically correspond to a new band (with a lot of technical complications that will only muddy the point).
Lastly, you're right about $E_n$ being bounded everywhere, and your reasoning is right as well. What was the question?