[Physics] Proof that energy states of a harmonic oscillator given by ladder operator include all states

harmonic-oscillatoroperatorsquantum mechanicsschroedinger equation

In quantum mechanics, while studying the harmonic oscillator, I learnt about ladder operators. And I realised that if you are able to find or determine any energy state of the quantum harmonic oscillator then, using the ladder operators, you can determine the other energy states as well. However in none of the texts I read I found the following fact:

The energy states determined by the above procedure, that is, using
the ladder operator are the only possible energy states of the
harmonic oscillator. There exists no energy state that is not given by the ladder operator.

So this is my question:

Are the energy states determined by the ladder operator in case of a
harmonic oscillator, the only possible energy states? Is any other energy state possible? And what is the
proof?

It is well known that the above-mentioned states are the only possible energy states but I want a rigorous proof that no other state is possible. However the analytical procedure mentioned in different books show an approximate solution of the Schrodinger equation which can be considered to be rigorous in the sense that it solves the equation to derive the solutions although it considers certain approximations.

I have searched for this answer in books related to quantum mechanics written by DJ Griffiths, Gasiorowicz, Dirac and online resources like OCW, University of Columbia's courses, caltech.edu, but I couldn't find a proper answer.

Best Answer

This is a fantastic question! Let's get started.

I will assume that we already have defined the ladder operators $a$ and $a^{\dagger}$ and have defined a "ground state" $|0\rangle$ (we still have not proved it is the ground state) such that $a|0\rangle=0$. We will also assume that we already know that the Hamiltonian of the Harmonic oscillator can be written in the form

$$H=\hbar\omega\left(a^{\dagger}a+\frac{1}{2}\right).$$

(Note that the ground state $|0\rangle$ is trivially an eigenstate with $E_0=\hbar\omega/2$.) Finally, I will assume that we have already shown the commutation relations of the ladder operators. Namely,

$$[a,a^{\dagger}]=1.$$

With this, we have enough for a proof.

We can define a state $|n\rangle$ (let's forget about normalization for now) as

$$|n\rangle=(a^{\dagger})^n|0\rangle,$$

where $n$ is a nonnegative integer. The state $|n\rangle$ is an eigenstate of the Hamiltonian with energy $E_n=\hbar\omega(n+1/2)$. We wish to show that the set $\{|n\rangle\}_{n\in\mathbb{Z}^+}$ are all of the possible normalizable eigenstates of the Hamiltonian.

Recall that in the position representation, if we have a potential $V(x)$, then we cannot have a normalizable eigenstate $|\psi\rangle$ whose energy satisfies $E_{\psi}\leq\min V(x)$. That is, we can not have an energy less than the minimum potential energy of the system (ie the kinetic energy must be positive).

Now, we finish off with a proof by contradiction. Consider an eigenstate $|\psi\rangle$ whose energy is given by $E_{\psi}=\hbar\omega(n+1/2+\epsilon)$, with $\epsilon\in(0,1)$. Such a state would essentially describe any of the "other" states that $H$ could permit. Now, consider the state $|\psi^{(1)}\rangle=a|\psi\rangle$. By the commutator algebra, it is not hard to show that $|\psi^{(1)}\rangle$ has energy

$$E_{\psi^{(1)}}=\hbar\omega\left((n-1)+\frac{1}{2}+\epsilon\right).$$

Now, we can induct and define a state $|\psi^{(m)}\rangle\equiv(a^m)|\psi\rangle$. Clearly, its energy is given by

$$E_{\psi^{(m)}}=\hbar\omega\left((n-m)+\frac{1}{2}+\epsilon\right).$$

Thus, unless this process terminates at some point (that is, $a|\psi^{(m)}\rangle=0$ for some $m$), we can achieve an arbitrarily low energy. However, this process could never terminate, since the ground state $|0\rangle$ is unique (it's defined in terms of a position operator and a single derivative operator, so $a|0\rangle=0$ simply defines a first order differential equation in position space) and has energy $\hbar\omega/2$, this cannot be achieved for any $\epsilon$ in the given range. Thus, no such state $|\psi\rangle$ can occur. Similarly, we cannot have a state with energy $E_{\psi}\in(0,\hbar\omega/2)$ by the same logic.

Thus, we have (very rigorously) shown that the only normalizable of $H$ are those with energy $\hbar\omega(n+1/2)$, which are uniquely made from the action of ladder operators on the ground state.

I hope this helped!

(TL;DR -- If another state did exist, it would have an energy not of the form of those given by ladder operators. However, acting on this state many times with $a$ would produce an arbitrarily low energy, and is thus such a state could not exist.)

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