[Physics] Pressure-Volume Diagram

phase diagrampressuretemperaturethermodynamicsvolume

Why does pressure start off high in the Pressure-Volume Diagram starting from a compressed liquid to a super heated vapor?

Noting that the temperature is constant in the process,I can't seem to understand why it would start at a high pressure going to lower pressure.

Meanwhile, I can understand the Temperature-Volume Diagram why temperature started of at a low value then increases eventually.

It seems that I am confused at the idea of changing saturation temperature and pressure. On the other hand, I understand the idea that boiling point and melting point temperatures can change if we are given with different pressures.

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Best Answer

Because liquids are in general much less compressible than gases, meaning that a small reduction in volume requires a big increase in pressure.

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