[Physics] Picking the different solutions to the time independent Schrodinger eqaution

quantum mechanicsschroedinger equationwavefunction

The time independent Schrodinger equation
$$-\frac{\hbar^2}{2m} \frac{d^2\psi}{dx^2}+V\psi = E\psi$$ can have many different solutions of $\psi$ for a particular value of $E$.

For example, if we found a complex solution $\psi(x)$ for a particular value of $E$, say $E_0$, we can write $\psi(x)=a(x)+ib(x)$. Then $a(x)$ and $b(x)$ will also be solutions to the T.I.S.E with $E=E_0$. Furthermore $c_1a(x)+c_2b(x)$ will also be solutions with $c_1$ and $c_2$ being arbitrary constants.

I read that one can always choose any of these solutions as the solution for the stationary state with energy $E_0$. But does that mean all these different solutions represent the same physical state of a particle?

The expectation value of any dynamical variable $Q(x,p)$ is given by
$\int \psi^*Q(x,\frac{\hbar}{i}\frac{d}{dx})\psi. $ How do we know for sure that $\int a(x)^*Q(x,\frac{\hbar}{i}\frac{d}{dx})a(x) $ and $\int b(x)^*Q(x,\frac{\hbar}{i}\frac{d}{dx})b(x)$ gives the same expectation values?

Best Answer

  1. In ordinary quantum mechanics, two wavefunctions represent the same physical state if and only if they are multiples of each other, that is $\psi$ and $c\psi$ represent the same state for any $c\in\mathbb{C}$. If you insist on wavefunctions being normalized, then $c$ is restricted to complex numbers of absolute value 1, i.e. number of the form $\mathrm{e}^{\mathrm{i}k}$ for some $k\in[0,2\pi)$.

  2. If $\psi(x) = a(x) + \mathrm{i}b(x)$ is a solution of the Schrödinger equation, then it is not automatically true that $a(x)$ and $b(x)$ are also solutions. It is "accidentally" true for the time-independent Schrödinger equation because applying complex conjugation shows us directly that $\psi^\ast(x)$ is a solution if $\psi(x)$ is, and $a(x)$ and $b(x)$ can be obtained by linear combinations of $\psi(x)$ and $\psi^\ast(x)$.

    There are now two cases: If $\psi$ and $\psi^\ast$ are not linearly independent - i.e. one can be obtained from the other by multiplication with a complex constant - then the space of solutions for this energy is still one-dimensional, and there's only a single physical state. If they are linearly independent, then there are at least two distinct physical states with this energy.

    Note that already the free particle with $V=0$ gives a counter-example to the claim that all solutions for the same energy have the same values for all expectation values. There we have plane wave solutions $\psi(x) = \mathrm{e}^{\mathrm{i}px}$ and $\psi^\ast(x) = \mathrm{e}^{-\mathrm{i}px}$ that are linearly-independent complex conjugates with the same energy that differ in the sign of their expectation value for the momentum operator $p$.