Physical Chemistry – How Neutral Water Molecules Attract by Electric Force to Form Water?

dipoleelectrostaticsmoleculesphysical-chemistrywater

If a water molecule is neutral, how do water molecules attract one another by electric force and form water?

This makes no sense to me (I'm new to physics) and my textbook didn't explain this well.

Best Answer

The water molecule is neutral on overall basis, i.e: the water molecule as a whole has no net charge.

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The water molecule is not linear rather it has a bent shape with two hydrogens on the same side. This happens because of the lone-pair-bond-pair repulsions.

The oxygen has is a more electronegative element than hydrogen, i.e: oxygen has high electron-attracting power. Therefore, it attracts the bond pair electrons towards itself which gives a partial negative charge to the oxygen and a partial positive charge to the hydrogen. This gives a possibility of the positive part of a molecule being attracted towards the negative part of another molecule. This is how water molecules attract each other. The bonds formed between the hydrogens and the oxygen are termed as hydrogen bonds and these are quite strong bonds which is why water with very low molecular mass has unusually high melting and boiling boint.

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As a matter of fact, even molecules with zero dipole moment can also attract each other. There exists weak Van der Waals forces (London Dispersion Forces) which are caused by induced dipoles. This is responsible for helium to to stay in liquid form at 4K.

London Dispersion Force - Induced Dipole Forces

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