[Physics] How to one describe electron motion around hydrogen atom

atomselectronshydrogenquantum mechanics

I remember from introductory Quantum Mechanics, that hydrogen atom is one of those systems that we can solve without too much ( embarrassing ) approximations.

After a number of postulates, QM succeeds at giving right numbers about energy levels, which is very good news.

We got rid of the orbit that electron was supposed to follow in a classical way ( Rutherford-Bohr ), and we got orbitals, that are the probability distribution of finding electron in space.

So this tiny charged particle doesn't emit radiation, notwithstanding its "accelerated motion" ( Larmor ), which is precisely what happens in real world.

I know that certain "classic questions" are pointless in the realm of QM but giving no answers it makes people asking the same questions over and over.

  • If the electron doesn't follow a classic orbit, what kind of alternative "motion" we can imagine?
  • Is it logical that while the electron is around nucleus it has to move in some way or another?
  • Is it correct to describe electron motion as being in different places around nucleus at different instants, in a random way?

Best Answer

The problem is that you're thinking of the electron as a particle. Questions like "what orbit does it follow" only make sense if the electron is a particle that we can follow.

But the electron isn't a particle, and it isn't a wave either. Our current best description is that it's an excitation in a quantum field (philosophers may argue about what this really means; the rest of us have to get on with life). An electron can interact with its environment in ways that make it look like a particle (e.g., a spot on a photographic plate) or in ways that make it look like a wave (e.g., the double slits experiment) but it's the interaction that is particle-like or wave-like, not the electron.

If we stick to the Schrödinger equation, which gives a good description of the hydrogen atom, then this gives us a wavefunction that describes the electron. The ground state has momentum zero, so the electron doesn't move at all in any classical sense. Excited states have a non-zero angular momentum, but you shouldn't think of this as a point like object spinning around the atom. The angular momentum is a property of the wavefunction as a whole and isn't concentrated at any particular spot.