[Physics] How to an electron shell hold more than two electrons

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The Pauli Exclusion principle states

in an atom or molecule, no two electrons can have the same four electronic quantum numbers. As an orbital can contain a maximum of only two electrons, the two electrons must have opposing spins.

So how can some electron shells have up to 6 electrons or more? Take the electron configuration of Magnesium. The 2p shell holds 6 electrons. How is this possible? Can you have multiple orbitals in a single electron shell?

Best Answer

A "shell" is the term for all states with the same principal quantum number $n$, but in each shell there are also possible different values for the angular momentum quantum number $0\leq \ell \leq n$, the magnetic quantum number $-\ell \leq m_\ell \leq \ell$ and the spin quantum number $m_s\in\{-1/2,1/2\}$.

So for $n>1$, 6 electrons in a shell do not violate the Pauli exclusion principle.

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