Photoelectric Effect – How Can a Photon Collide with an Electron? Exploring Photons and Electrons

electronsphotoelectric-effectphotons

Whenever I study the photoelectric effect and the Compton effect, I have always had a question about how a photon can possibly collide with an electron given their unmeasureably small size. Every textbook I've read says that the photo-electrons are emitted because the photons collided with them. But since the photons and electrons virtually have no size, how can they even collide? I have searched for the answer on the internet but I couldn't find any satisfying one.

Best Answer

This is an answer by a particle physicist that has been working with data for forty years:

Photons and electrons are quantum mechanical entities, and to really really understand their interactions, quantum mechanics has to be invoked.

When detected, the photon has a point particle footprint (as does the electron) consistent with the axiomatic particle table of the standard model.

The leftmost frame shows the collision of a countable single photons on a screen (in a double-slit experiment).

Singlephot

The accumulation of photons (light emerges in a calculable manner from many photons), shows the wave nature's interference effects. It is the probability of landing on the (x,y) of the screen that displays a wave behavior. Not the individual photons.

Here is another measurement of a photon

Gamma

The original picture is here. That the single photon (gamma) electron interaction is at a point is evident.

Now let us see how what we call size for macroscopic particles in quantum mechanics appears. It is all dependent on probabilities of a particle being at an (x,y,z) to interact with another particle. Look what an electron around a hydrogen atom has as a probable location:

Orbitals

This is what defines the macroscopic charge distribution, and the probability of an incoming gamma ray to interact with the electron is a mathematical combination of this, and the coupling constants of the quantum mechanical interactions.

A free electron has a very small probability to be hit by a photon. That is why high density beams are used in high energy experiments. In general it will be the coupling constants which will give high probabilities the closer the two point particles are, and of course not to forget Heisenberg's uncertainty principle, which also will define a volume in space and momentum where interactions can happen.

The photoelectric effect involves electrons that are in orbitals and a large number of atoms and molecules, and the fact that it exists means that there is enough probability for an incoming photon to hit an electron in the orbitals distributions of the specific solid.