Relative humidity equals actual water vapor pressure divided by saturated water vapor pressure. As temperature goes up, saturated vapor pressure goes up as well, and relative humidity will go down, if absolute humidity remains the same. The exact relationship must be measured.
Heat of vaporization is related to enthalpy change, while dew point is related to free energy change, i.e. enthalpy plus entropy. That's why they are very different concerning relative humidity.
The enthalpy of a gas is more-or-less independent of pressure or partial pressure, because gas molecules don't really interact with each other. At insanely-high pressures there would be some effect on enthalpy of course, but the effect at everyday pressures is very low. Pressure mainly affects a gas via entropy not enthalpy.
The enthalpy of a liquid is somewhat dependent on total pressure: A high pressure will push the molecules closer together and therefore change their interaction energies. But obviously the enthalpy of the liquid doesn't depend on what the gas partial pressures are, it can only depend on the liquid's own total internal pressure.
So the answer is: Heat of vaporization, being related to enthalpy not entropy, has essentially no dependence on relative humidity. (given a constant total air pressure)
-- UPDATE --
Oops, whenever I wrote "enthalpy" I should have said "enthalpy per molecule" or "enthalpy per mole" ["molar enthalpy"]. You can check for yourself that the enthalpy per molecule of an ideal gas is independent of pressure or partial pressure. For a real-world gas, it's approximately independent. The "per mole" quantities are what matter for dew point etc.
Best Answer
I think, this question more specific to meteorology and climatology than pure physics, but definitely can be answered in physics terms with some meteorological comments. Thereby, your question can be redefined as: How relative humidity, temperature, pressure and height relates to level of precipitation?
Firstly, we should look at basic ideas to understand this relations. Meteorology studies atmosphere, which includes air and it's fluctuations. In the same time, air is a mixture of gases. As any other gas, it can be described in physical quantities like temperature, pressure, density.
Pressure relations
Air near Earth surface is moist. It means that in air mixture exist water vapor, besides other gases. In higher parts of atmosphere air doesn't have a lot of water vapor, so it is called dry.
Water vapor, as any other gas, creates pressure. Pressure of vapor proportional to it's density and absolute temperature. Pressure of water vapor in saturation condition $E$ called saturated vapor pressure,described by Magnus equation: $$ \ E = \ E_0* 10^{at/b+t}\,, $$ where $E_0 = 6,107\ Pa$ at $t = 0^{\circ}C$, $a = 7.45$ and $b = 235$ - are empirical coefficients. For example, $a =7.6326$, $b = 241,9$ over-water.
Relative humidity can be described as: $$ \ f = \ (e/E)* 100\%\,, $$ where $e$ is actual partial pressure, $E$ - saturated vapor pressure, described in previous equation. For example, with temperature $20^{\circ}C$ saturated vapor pressure $E=23.4\ hPa$ (!)
Thereby: $$ \ f= (e / E_0*10^{at/b+t}) * 100\% \,. $$
Relative humidity(RH), $f$ described in last equation, which combines with Magnus equation and gives relation between temperature and RH. Note that coefficients $a$ and $b$ differs from location to location and maximum in equatorial zone over open ocean.
Height relations
Next interesting parameter is lapse rate, which describes decrease of temperature with rise of height. The thermodynamic state of a moist air parcel changes through vertical motion. Vertical displacement alters the environmental pressure, which varies hydrostatically.
Vertical motion cooling off water vapor and at some point start condensation, which is point of saturation or Dew point, and change it's state to water. This process described by dry-adiabatic gradient and moist-adiabatic gradient.
Under saturated conditions, the adiabatic description of air breaks down due to the release of latent heat that accompanies transformation of water from one phase to another. This is describes as LCL. LCL is formally defined as the height at which the relative humidity (RH) of an air parcel will reach 100% when it is cooled by dry adiabatic lifting.
Conclusion
Based on this information, we can now understand that higher RH means that in air mixture exists more water particles, which evaporate from water around. With rise of temperature air floats up in atmosphere where it's condensate due to adiabatic law and water particles change their state and organize clouds, if in this period of time came cyclone, which is area of low pressure, there will be no forces to maintain cloud condition, which leads to rainfalls. Note, that clouds can be created in one place but move to significant distances.
Sources:
Information gathered from Fundamentals of Atmospheric Physics by Murry L. Salby and couple of books about meteorology in Russian.
Also. related research paper Dependence of precipitation on temperature at Florence and Livorno (Italy)