[Physics] How heat flow through finite temperature drop is an irreversible process

heat-enginereversibilitytemperaturethermodynamics

Is it necessary that the drop/rise in temperature by flow of heat is irreversible?

Best Answer

A heat flow through a finite difference of temperature is irreversible because it does not satisfy the definition of reversibility.

A thermodynamic process is reversible if an infinitesimal change of the external conditions reverses the process. To illustrate, let us consider a system at temperature $T$ in thermal equilibrium - that is at the same temperature - with a thermal reservoir. An infinitesimal increase of temperature $dT$ of the reservoir causes a heat flow to the body, which heats up by the same $dT$. If the external condition is now reversed, i.e. there is an infinitesimal decrease of the reservoir's temperature, then the heat flow also reverses, it goes from the body to the reservoir.

This will not happen for a finite temperature difference. Let us say the reservoir is $1+dT$ degree above the body. The heat flows to the body. Decrease the reservoir's temperature by $dT$ and the heat flow does not reverse. This is what meant by irreversible heat exchange.

Note that this definition is of crucial importance when dealing heat engines. This reversibility is what allows, for example, a Carnot heat engine also works as a Carnot refrigerator.

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