[Physics] How does quantization solve the ultraviolet catastrophe

quantizationradiationsingularitiesthermal-radiation

I understand how classical physics leads to the UV catastrophe. But I cannot understand how quantization solves it.

  • How can quantization prevent the body from radiating a lot of energy?

I know this question is similar to many other questions but I need a layman's explanation (without too much mathematical details).

  • Finally why does the peak reach zero intensity after a certain frequency?

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Best Answer

Avoiding mathematical formulae to the maximum, and warning for furious hand-waving ahead, I would state it like this:

In the classical picture, there is no quanta concept, so you could have just a little bit of radiation energy at any frequency. However, since quantization appeared, the minimum amount of radiation energy that you could possibly have at a frequency $\nu$ is $h\nu$. Since the temperature regulates the distribution of energy by the Boltzmann equation ($\mathbb{P}(E)\propto e^{-E/kT}$), if you have radiation at a certain frequency such that $h\nu\gg kT$, then having just one photon is "too much", or it is highly unlikely.

Alternatively, we know from statistical mechanics that it is very unlikely to have radiation with energy higher than $kT$, with the precise expression for this statement given by Boltzmann law. But for $h\nu\gg kT$ type of radiation, Planck leaves us no choice: you have to have more than one photon, or none. Therefore, you almost do not have this type of radiation (or these type of photons) when the temperature is low, therefore "depopulating" the UV states.

Now I realize something: Planck could have "solved" the UV catastrophe by postulating not complete quantization, but only that the minimum amount of energy at a certain frequency is $h\nu$. With this "floor", you do not need to go further and say that the energy has to come on integer multiples of this minimum quantity, just that, if energy of radiation at this frequency exists at all, then it has a minimum $h\nu$.

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