Atmospheric Science – How Does Carbon Dioxide or Water Vapour Absorb Thermal Infrared Radiation from the Sun?

atmospheric science

We are all told at school water vapour and carbon dioxide are the top two greenhouse gases, and that they absorb thermal infra red radiation, trap heat and warm up the Earth. My question is how do they do that? Why can't Oxygen or Nitrogen or any other gas not absorb infra red radiation as well as water vapour or CO2?

Best Answer

The absorption of IR radiation is due to vibrations of molecules. When a vibration causes change in charge distribution (or dipole moment to be more specific) the IR radiation is absorbed.

Generally, hetero-polar molecules, like $\rm H_2O$ and $\rm CO_2$, have permanent dipole moment. The external oscillating electric field in this case perturbs the Hamiltonian and causes IR absorption. Hence, they contribute to "Green House effect" by absorption of heat.

$\rm H_2O$, which is non-linear molecule, has three fundamental modes of vibrations. Symmetrical Stretching, asymmetrical Stretching and scissoring (bending). $\rm CO_2$, which is linear molecule, has four fundamental modes of vibrations. Symmetrical stretching, asymmetrical stretching and two degenerate scissoring modes, in planes perpendicular. The symmetric stretching mode in $\rm CO_2$ does not produce or absorb any IR, as it does not cause change in dipole moment, but other modes do change charge distribution causing absorption of IR.

Well, the homo-polar molecules, like $\rm N_2$ and $\rm O_2$, does not have any permanent dipole moment. The external oscillating electric field does not perturb the Hamiltonian for nuclear motion, and does not absorb IR, though it perturbs Hamiltonian for electronic motion. Hence, do not contribute for "Green House effect".

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