Heat Pump COP (Coefficient of Performance)
$$COP=1-\frac{T_c}{T_H}$$
With Heat Pumps is the efficiency/COP more dependent on the hot or the cold reservoir and why?
carnot-cycleheat-enginetemperaturethermodynamics
Heat Pump COP (Coefficient of Performance)
$$COP=1-\frac{T_c}{T_H}$$
With Heat Pumps is the efficiency/COP more dependent on the hot or the cold reservoir and why?
Short answer: You cannot construct a reversible ($\delta S_{cycle}=0$) cycle when $T_H<0,T_C>0$. So the expression for the efficiency doesn't apply.
For the long answer we have to go through the derivation of the eficiency of the Carnot cycle. As usual, one have to pay a lot of attention to signs. We have energy changes in heater and cooler related to their entropy changes: $$\delta E_H=T_H\delta S_H,\quad \delta E_C=T_C\delta S_C$$ The heater looses energy, while the cooler receives it: $$\delta E_H < 0,\quad \delta E_C >0$$ So the work done by a working body that transfers energy from heater to cooler is: $$\delta A = -\delta E_H - \delta E_C > 0$$ The efficiency of a cycle is a relation of the work done ($\delta A>0$) to energy lost by the heater ($-\delta E_H>0$). $$\eta = \frac{\delta A}{-\delta E_H} = 1 + \frac{\delta E_C}{\delta E_H}=1 + \frac{T_C}{T_H}\frac{\delta S_C}{\delta S_H}$$
In "ordinary" case: $T_H>0, T_C>0$ we, consequently, have: $$ \delta S_H<0,\quad \delta S_C>0$$ And we provide an example of an invertible cycle (the Carnot cycle), which, therefore, have to obey: $$\delta S_{cycle} = \delta S_H+\delta S_C = 0 \quad \Rightarrow \quad \frac{\delta S_C}{\delta S_H} = -1$$ Which leads to the usual formula.
If the heater have negative temperature: $T_H<0, T_C>0$ we will have: $$ \delta S_H > 0,\quad \delta S_C>0$$ So there is no way you can create a cycle with $\delta S_{cycle}=0$. The only thing you can say is that: $$\frac{\delta S_C}{\delta S_H}>0 \quad \Rightarrow \quad \frac{T_C}{T_H}\frac{\delta S_C}{\delta S_H}<0 \quad \Rightarrow \quad \eta<1$$
How is the efficiency of a heat engine related to the entropy produced during the process?
The maximum efficiency for any heat engine operating between two temperature $T_H$ and $T_C$ is the Carnot efficiency, given by $$e_C = 1 -\frac{T_C}{T_H}.$$
Such a heat engine produces no entropy, because we can show that the entropy lost by the hot reservoir is exactly equal to the entropy gain of the cold reservoir, and of course, the system's entropy on the net doesn't change because the system undergoes a cycle.
Any heat engine operating between the same two temperatures whose efficiency is less than $e_C$ necessarily increases the entropy of the universe; in particular, the total entropy of the reservoirs must increase. This increase in entropy of the reservoirs is called entropy generation.
Finally, the efficiency of the perfect engine is less than one, necessarily, because the entropy "flow" into the system from the hot reservoir must be at least exactly balanced by the entropy "flow" out of the system into the cold reservoir (because the net change in system entropy must be zero in the cycle), and this necessitates waste heat from the system into the cold reservoir. The fact that $e_C$ goes to one in the limit of small ratios $T_C/T_H$ is a consequence of the fact that $Q_C$ is small compared to $Q_H$. It is not a consequence of the fact that entropy generation is small in this case, because entropy generation is already zero for the Carnot cycle.
Let's concentrate first on the interaction between the system and the hot reservoir. An amount $\delta Q_H$ of energy flows into the system from the hot reservoir, which means that the system's entropy changes by $$\mathrm dS_\text{sys} = \frac{\delta Q_H}{T_\text{sys}},$$ and correspondingly, the reservoir's entropy changes by $$\mathrm dS_\text{hot} = -\frac{\delta Q_H}{T_{H}}.$$ It is straight-forward to show then, that the total change in entropy of system plus environment satisfies $$\mathrm dS = \mathrm dS_\text{hot}+\mathrm dS_\text{sys} \geq0,$$ with equality holding if and only if the system and environment exchange energy via heating when they have equal temperatures, $T_\text{sys} = T_H$.
As a consequence, in order to minimize entropy production (and, in fact zero it out completely) during this process, we want $T_\text{sys} = T_H$, and the net change in system entropy during this process can then be written as $$\Delta S_\text{sys} = \int \frac{\delta Q_H}{T_\text{sys}} = \frac{Q_H}{T_{H}},$$ since we are assuming that the temperature of the reservoir doesn't change at all during the cycle.
Now, since the system operates on a thermodynamic cycle, and since the system entropy $S_\text{sys}$ is a state variable (state function/$dS$ is an exact differential, etc.), it must be true that $$\mathrm dS_\text{sys,cycle}=0.$$ Therefore, there must be some other process during which the system expels an amount of energy $Q_C$ to some other reservoir via heating in such a way that the change in system entropy during this new process is the negative of the change in system entropy that we calculated before. By the same argument as above, it must be that this change in entropy is $$\Delta S_2 = -\frac{Q_C}{T_C},$$ where $T_C$ is the temperature of the cold reservoir.
Finally, then, since system entropy is a state variable, $$0 = \Delta S + \Delta S_2 = \frac{Q_H}{T_H}-\frac{Q_C}{T_C}.$$ Another way of looking at this equation is that the net change in entropy of the hot reservoir is negative the net change in entropy of the cold reservoir during the cycle, and hence the net change in entropy of the universe is zero during the cycle.
Now, none of this seemed related to the fact that efficiency goes to 1 as the ratio of $T_C$ to $T_H$ goes to zero. This comes in in the following way. First, the net work output during one cycle is $$W_\text{out} = Q_H-Q_C,$$ and hence the efficiency of the engine that we've just made is $$e = \frac{W_\text{out}}{Q_H} = 1 - \frac{T_C}{T_H},$$ after some algebra. Based on our calculation above, this must be the maximum efficiency of any engine operating between these two temperatures. However, if we change the temperatures, then we can change the efficiency. The reason the efficiency goes up as the temperature ratio goes down is that $W_\text{out}$, being the difference between the heat flows, must go up if, say, we lower $T_C$ (because then $Q_C$ goes down) or if we raise $T_H$ (because then $Q_H$ goes up).
In some sense, this part really doesn't have much to do with entropy at all, because from the thermodynamic perspective, entropy production (which is the increase in entropy of an isolated system) is a measure of how much work we could have done if we had done the process reversibly, but we have already designed the perfect engine operating between those two particular temperatures above, so entropy doesn't have anything else to say.
Best Answer
Actually the formula given in your question describes the thermal efficiency $Nth$ of a device , usually a heat engine that transforms thermal energy into mechanical energy and it's always: $Nth<1$.
On the other hand $COP$ or coefficient of performance is the ratio $Q/W$ of the device called heat pump, where $Q$ is the heat removed from the cold reservoir and $W$ the input work required in order to remove this heat (usually electrical energy).
For a heat pump operating at maximum theoretical efficiency (i.e. Carnot efficiency), it can be shown that: $COP=Q/W=Thot/(Thot-Tcold)$.
Because heat pumps do not transform one form of energy to another but in fact they transfer heat from a cold reservoir to a hot reservoir,COP can and usually has a value much greater than $1$.
Notice also that the $COP$ term is commonly used to describe the performance of a heat pump device, when it is operating in heating mode.
Now about your question: Let's assume that a heat pump is operating at $Tcold=273K$ and $Thot=290K$ so $ΔΤ=17K$ and $COP=290/17=17.06$
Now let's assume that the same device operates at the same $ΔΤ=17K$ but the reservoirs temperatures are 10 degrees higher. In this case $COP=300/17=17.67>17.06$.
This means that our device is more efficient if the temperature of cold reservoir is greater (in heating mode), something expected because physically is more difficult to 'pump' or remove heat from a colder reservoir-enviroment.
It's obvious that the COP performance of a certain device depends on the enviroment conditions and it's value usually varies between 2.5 and 5