[Physics] generating the hydrogen that has exploded in the Fukushima reactor

nuclear-engineering

The explosions at the Fukushima nuclear reactors were caused by a build of hydrogen. I was wondering where this hydrogen came from.

This question Fukushima – Isn't the hydrogen presence a proof of meltdown? suggests that the hydrogen is caused by thermolysis of water.
But surely this can't be the case? If it were, wouldn't it require the hydrogen and the oxygen to be separated whilst they cooled – else they would recombine into water in a more gradual fashion as the gases cool once they are clear of the scorching hot fuel rods?

Best Answer

This was (one of the few) facts reported clearly and correct in German news.

The Zirconium metal of the fuel tubes reacts with water vapor at elevated temperatures (above 1200 °C if I remember correctly) The reaction is simply: Zr + 2 H2O => ZrO2 + 2 H2 This is proof, that parts (at least) of the fuel rods were not immersed in water, but it does not prove melting.

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