[Physics] Examples where an ill-behaved function leads to surprising results

mathematical physics

In mathematical derivations of physical identities, it is often more or less implicitly assumed that functions are well behaved. One example are the Maxwell identities in thermodynamics which assume that the order of partial derivatives of the thermodynamic potentials is irrelevant so one can write.

Also, it is often assumed that all interesting functions can be expanded in a Taylor series, which is important when one wants to define the function of an operator,
for example
$$e^{\hat A} = \sum_{n=0}^\infty \frac{(\hat A)^n}{n!}.$$

Are there some prominent examples where such assumptions of mathematically good behavior lead to wrong and surprising results? Such as… an operator $f(\hat A)$ where $f$ cannot be expanded in a power series?

Best Answer

I think, the most transparent example is phase transition: by definition it is when some thermodynamic value does not behave well.

AFAIK when Fourier showed that non-continuous function may be presented as an infinite sum of continuous, he had a hard time convincing people around that he is not crazy. That story might partially answer your question: as long as any not-so-well-behaved function may be presented as a sum of smooth ones, there is no much difference as long as good formulated laws are linear. Functions which are really bad behaved usually do not appear in real problems. If they do, there is some significant physics behind it (as with phase transition, shock wave, etc.) and one can not miss it.

For an operator it is better (for physicist) to think of function from operator as a function acting on its eigenvalues (if it is not diagonalizable, in physics it is bad behaviour). This is equivalent to power series definition, but works for any function.

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