Thermodynamics – Entropy Generation of Constant Volume Heat Addition Process

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For an ideal gas constant volume heat addition process, change of entropy equation is:

$$\Delta S= c_v \ln\frac{T_2}{T_1}+ R \ln\frac{v_2}{v_1}= \int \frac{dq}{T}+S_{gen}$$

The term $R \ln\frac{v_2}{v_1}$ equals zero, since it’s a constant volume process.

For ideal gas $\int \frac{dq}{T} =c_v \ln\frac{T_2}{T_1}$ .

Then:

$$\Delta S= c_v \ln\frac{T_2}{T_1}= c_v \ln\frac{T_2}{T_1}+S_{gen}$$

Therefore, the $S_{gen}$ term equals zero and the process is reversible.

The question is: why does the $S_{gen}$ term equal zero and the process is reversible when this is a heat addition through a finite temperature difference?

To give a numerical example, imagine that an ideal gas is put in a rigid tank of uniform temperature where its initial temperature is $400$ K, and a hot reservoir at $500$ K. then heat is transferred from the hot reservoir to the rigid tank until the temperature of the rigid tank is $430$ K.

referring to the expressions above $T_1 =400$ K and $T_2 =430$ K.

Best Answer

The $S_{gen}$ term is not equal to zero. The equation you used to calculate $\int{dq/T}$ was applied improperly. The T in this equation should be the temperature at the boundary interface between the gas and its surroundings (where the heat transfer dq is occurring), $T_B$, not the temperature of the gas T: $$\int{\frac{dq}{T_B}}$$ For example, if the gas is being heated by contact with a reservoir at $T_{res}$, then $T_B=T_{res}$. Unfortunately, this critical requirement is almost always omitted in thermodynamics textbooks. For more details on this, see Fundamentals of Engineering Thermodynamics by Smith and van Ness.

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