[Physics] Does there always exist a reversible path between two states

entropyreversibilitystatistical mechanicsthermodynamics

For a reversible process it holds that $dS=\delta Q/T$. We thus get the fundamental relation of thermodynamics: $dS=dU/T+P/T dV$. The reasoning goes that because entropy is a state function, this relation holds even for irreversible processes because we can imagine that there is a reversible path between the two states.

But how do we know there exists a reversible path between two given states?

Best Answer

There is not just one reversible path between the initial and final thermodynamic equilibrium states of a system. There are an infinite number of reversible paths, and they all give the exact same value for the change in entropy (as well as for the changes in the other thermodynamic functions). The integral of $dq/T_{boundary}$ for all these paths is also greater than the corresponding integral for any irreversible path, where $T_{boundary}$ is the temperature at the boundary between the system and its surroundings. This is known as the Clausius inequality.