[Physics] Does metal sublimate

material-science

I know that solid water (ice) sublimes ("evaporates" straight from solid to dissolved gas) in air. On the other hand, some metal objects seem to last forever (e.g. gold, stainless steel and other metals that don't tarnish, rust, etc.) So, does solid metal sublime? And if not, why not, darn it!

Best Answer

They do actually, but in normal conditions you can not observe this. The sublimation rate will depend on temperature and energy of sublimation, which is different for different metals. Also in normal conditions you will have some kind of equilibrium - some of the particles that leave the surface will condensate back. But in vacuum techniques you need to take this to account - there are metals with low sublimation energy - such as Zinc, Magnesium, Cadmium e.t.c. You can see them here, here, for example, in the list of non-suitable for vacuum equipment. As an extreme case you can imagine a piece of metal, which is heated from inside and put into deep space, if its mass is small and gravitation attraction can be neglected, it will evaporate.