[Physics] Do electrons collapse into nucleus, if electrons in the atom are constantly excited

atomic-physicsatomsenergyquantum mechanics

From the Bohr's atomic model, it is clear that electron can have only certain definite energy levels. When the electron is present as close to the nucleus as possible, the atom has the minimum possible energy and is said to be in the ground state. When energy from some outside source is supplied to it, it can absorb a definite amount of energy and jumps to higher energy state. Such a state of an atom in which the atom possesses more energy than possessed in the ground state is called excited state. These excited states are unstable and the electron tends to come back to lower energy level. This transition (change) from upper to lower energy level occurs with a jump and energy is emitted in the form of a quantum equal to difference in energies between the two levels.

I have a doubt here, if electron absorbs energy from the outside source and jumps to the higher energy state, it will be now storing absorbed energy, as potential energy at the excited state. If electron emits all the absorbed energy (quanta-difference in energies between the two levels). By virtue of what energy does electron come down? I mean, in common situations, we say that an object at any height comes down converting it's potential energy into kinetic energy. Here in case of electron, it has already emitted absorbed energy as quanta. So, is it that electron losses some energy other than the energy absorbed from the source, to come down to ground state. I thought, if it was a possibility, then electron would constantly need to lose energy, whenever excited, at last, it would collapse into the nucleus. But, this not we really observe. I think there might be some misunderstanding by me or there might be any of the existing model like quantum mechanical model, which could account for this. If any were the case, please explain.

Best Answer

Based on some of your comments, I think what might be tripping you up is the first statement you started with:

From the Bohr's atomic model, it is clear that electron can have only certain definite energy levels.

and

...If suppose, we assume electron losses total energy, electron can't stay in any particular shell, as it would not have that particular value of energy.

That may be true for Bohr's atomic model, but Bohr's atomic model is wrong. And electron does not have to be in a particular, definite shell or energy level. Rather, any electron state is a superposition of states of definite energy level (energy eigenstates).

That means the expectation value of a hydrogen electron state is going to look like $$\langle E\rangle = \sum_n |a_n|^2 E_n\text{,}$$ where $\{a_n\}$ are arbitrary complex values with $\sum_{n>0}|a_n|^2 = 1$ and $E_n$ are energy levels in increasing order. Because of the sum-to-$1$ condition, taking any portion along the other energy eigenstates will increase energy compared to the ground state.

In other words, even if the electron state does not have a definite energy, you still can't go lower than the ground state.

Suppose, I have a cup of hot coffee on the table. It will be continuously losing energy in the form of heat, but it stays on the table, though there was a energy loss. Now, all of a sudden, I take off the table, the cup of coffee converts it potential energy into kinetic energy to come down.

If you don't shake the table, the coffee cup will sit there, forever. Similarly, nothing perturbs the electron in an excited energy eigenstate, then it simply will never decay. It cannot: energy eigenstates are stationary; they do not evolve into anything other than themselves.

However, being completely without external perturbation is actually impossible. The uncertainty principle provides the electromagnetic field with vacuum fluctuations, which will perturb the electron even if nothing else in the environment does. In your analogy, this (or something else) provides the "shaking of the table" for the electron. Once the electron state gains even a tiny component in some other energy eigenstate, the state can evolve in time.

In other words, one can think of spontaneous emission as a particular type of stimulated emission where it's the vacuum that does the perturbing.