[Physics] Causes of entropy change

entropyreversibilitystatistical mechanicsthermodynamics

My sir told me entropy change due to two reasons

  1. entropy created

  2. entropy due to heat exchange

Prof also said that entropy produced is zero for reversible process but not for irreversible process.

But I do not understand how they both are different. I am getting confused.

Can anybody explain me this with an example each?

Best Answer

Your professor is using a framework in which the entropy change of a closed system is equal to the sum of the entropy created within the system (by irreversibilities, such as viscous dissipation) plus the entropy entering and leaving the system through its boundaries. The entropy entering through each boundary of the system is given by $Q/T_\textrm{boundary}$ where $Q$ is the heat passing through that part of the boundary and $T_\textrm{boundary}$ is equal to temperature at the boundary through which the heat is flowing. So, in this framework, $$\Delta S=S_\textrm{created}+\sum{\frac{Q}{T_\textrm{boundary}}}$$ If the process is reversible, then $S_\textrm{created}=0$ and $T_\textrm{boundary}=T$, where T is the (uniform) temperature of the system.

For more on this powerful approach, see Fundamentals of Engineering Thermodynamics by Moran et al.