Quantum Mechanics – How Angular Momentum Conservation Works

angular momentumconservation-lawsquantum mechanics

In Classical Mechanics it is "easy", if some system has some angular momentum at the beginning then conservation of angular momentum means that no matter what happens, the angular momentum vector at the end will be the same.

In Quantum Mechanics it is different because we cannot even know the angular momentum of a system. We can only know its magnitude $L^2$ and one of its components, say $L_z$. So we cannot talk about the conservation of angular momentum as implying that the initial vector must be the same as the final vector. We don't know such vector.

So how do we apply the conservation of angular momentum?

  • The mean value of the vector $\langle \vec{L} \rangle$, of which we know exactly the three components, is the magnitude that is conserved? What about other quantities related to angular momentum, such as its dispersion $\sigma_L$?
  • Is the angular momentum ket of a system the thing that is conserved? I mean, if a system is in some eigenstate of angular momentum $|j,m\rangle$, is this property of the system the one that does not change due to conservation?

Best Answer

In QM, angular momentum is conserved as an operator.

Deal with it.


This is best seen in the Heisenberg picture, where the equation of motion for $\hat{\mathbf L}$ in a spherically-symmetric hamiltonian $\hat H$, $$ i\hbar\frac{\mathrm d}{\mathrm dt}\hat{\mathbf L} = [\hat{\mathbf L},\hat H] = 0, $$ so $\hat{\mathbf L}$ is conserved as an operator as $t$ goes from $t=0$ onwards. In particular, this means that:

  • If the system is in an eigenstate of a function of $\hat{\mathbf L}$ (including the magnitude $\hat{L}^2$ or any components) then it stays in that eigenspace for all time.
  • If the system is in a superposition of such eigenstates, then the weights and relative phases of that superposition are maintained.
  • This then implies that all moments of all distributions of observables that are a function of $\hat{\mathbf L}$ are constant in time.

These conclusions also hold equally well in the Schrödinger picture.

(On the other hand, if you know that the system is in some eigenstate $|\psi⟩$ of $\hat L^2$ and $\hat L_z$ and it evolves under a spherically symmetric hamiltonian $\hat H$ in the Schrödinger picture, you can conclude that it will remain as an eigenstate of $\hat L^2$ and $\hat L_z$ with its same eigenvalues, but you cannot conclude that the state does not change, as there is typically radial motion which can obviously change.)

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