Newton’s third law in thermodynamics

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In my physics textbook, the foundation for work is derived using newton's third law, where F_surr = – F_gas, where surrounding represents a piston-cylinder device and gas is pushing against the inner surface of the piston towards the right.

My questions are:

  1. Given this information, it is obvious that W_surr = – W_gas. So, shouldn't the terms cancel each other and result in zero acceleration of the piston, i.e., the piston remains stationary?
  2. I understand that newton's third law is applicable for forces acting on different objects in contrast to second law which is used for analysing forces acting on a single object. So using second law, if i were to dissect the system and piston into two bodies and assuming no friction, we will have F_surr acting towards the left on the gas and F_gas acting on the piston towards the right. So, I am confused here, shouldn't F_surr being the only force on the gas cause it to compress and F_gas on the piston cause the piston to move towards the right?
  3. Finally, during a quasi-equilibrium process, will there be any accelerations of the piston at all at each equilibrium states or is the equilibrium state like a point at which the system and surrounding are in complete mechanical equilibrium and are stationary?

Essentially, I am having a hard time applying newton's second and third law to derive work equations.

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Best Answer

For question 1, when we do a force balance on a body, we include only the forces exerted by other bodies on that body, and not forces which it exerts on other bodies. So the two action-reaction forces you refer to do not cancel.

For question 2, in the first law of thermodynamics energy balance, $\Delta U=Q-W$, W is the work that the gas does on the piston. So $W=F_{gas}\delta$, where $\delta$ is the displacement to the right. The magnitude of the surroundings force on the gas $F_{surr}$ is equal to the magnitude of the gas force on the surroundings $F_{gas}$ (although it is pointing to the left). Based only on the magnitude of the surrounding force, the work that the gas does on the surroundings is $W=F_{surr}\delta$.

For question 3, in a quasi-static process, the piston is not accelerating and gaining kinetic energy; the system and surroundings are essentially in mechanical equilibrium (except for a slight, quantitatively insignificant, difference).