Superconductivity – Mermin-Wagner Theorem and Its Implications

critical-phenomenaphase-transitionstatistical mechanicssuperconductivitysymmetry-breaking

Why can superconductivity exist in 2D since Mermin-Wagner should forbit it? This question was asked here before, but I don't think anyone gave a satisfactory answer, so let me revisit it.

I have read both the rigorous proof of BCS/Hartree-Fock (1) and that of the quantum Mermin-Wagner (2). Of course, the two rigorous statements don't exactly exclude each other. However, on a conceptual level, it seems hard to reconcile. Indeed, superconductivity breaks $U(1)\cong SO(2)$ gauge symmetry at some finite temperature $T>0$ for all spatial dimension $d\ge 1$, but this is in principle forbidden by Mermin-Wagner since it doesn't allow any continuous symmetry breaking at finite temperatures for $d\le 2$.

There's also this explanation, but I don't quite understand its answer. Mathematically speaking, a 3D system that is translationally invariant in 1 dimension is equivalent to a 2D system so I don't quite understand why it matters. Although anyons are the correct way to describe statistics in a 2D system, the mathematical formalism of fermions/bosons do exist (not to mention that fermions/bosons are also types of anyons). Finally, the only way for the $U(1)$-symmetry to not have long range order (the phase of the complex order parameter $\psi$) seems to be that the amplitude $|\psi|=0$, so superconductivity indeed seems to be a long-range order phase transition (correct me if I'm wrong).

  1. Bach, V., Lieb, E.H. & Solovej, J.P. Generalized Hartree-Fock theory and the Hubbard model. J Stat Phys 76, 3–89 (1994). https://doi.org/10.1007/BF02188656

  2. http://www.scholarpedia.org/article/Mermin-Wagner_Theorem

Best Answer

All the answers here and in the other question do not address the important difference between superconductivity and superfluidity: namely that the Nambu-Goldstone modes in superconductors are not gapless. The latter is an assumption for the validity of the Mermin-Wagner-Hohenberg-Coleman theorem, and therefore it does not apply.

The question of whether superconductivity can exist in a strictly 2D system turns out to be very interesting. Let's go in steps:

  1. The Mermin-Wagner-Hohenberg-Coleman theorem precludes true long-range order in 2 dimensions (at finite temperature) or 1 dimension (at zero temperature). The reason, as is clear from Coleman's proof, is that that the fluctuations of linearly dispersing scalar modes, c.q. Nambu-Goldstone modes, in 2+0 or 1+1D are so violent as to preclude their existence altogether. This is due to an infrared divergence, so this applies to long wavelengths/large systems.

  2. However, the Nambu-Goldstone modes in a superconductor are gapped by the Anderson-Higgs mechanism (due to the coupling to gauge fields, the electromagnetic field). Therefore, there is no infrared divergence (the $k^2$ term in the denominator is replaced by $k^2 + (\hbar\omega_{\rm{p}}/c)^2$, with $\Delta$ the superconducting gap with $\omega_{\rm{p}}$ the plasma frequency). The theorem does not apply.

  3. So there seems to be no obstruction to superconductivity in any low dimension. But this does not take into account the topological defects (vortices). In 2D superfluids, there is the BKT phase transition between a low-temperature, quasi-long-range ordered phase, where vortex pairs are bound, and a high-temperature, disordered phase, where vortex pairs are unbound. The transition temperature is set by the balance between the energy cost of a vortex pair (which grows logarithmically with system size) and the entropy gain of having thermally excited pairs (which also grows logarithmically with system size). But in superconductors, the size of a vortex is capped by the inverse of the superconducting energy gap $\Delta$. Conversely, the entropy gain is unaffected. Therefore the argument leading to the BKT phase transition does not apply, and the transition temperature is pushed to zero as the system size grows. In an infinite volume, vortices are unbound at any temperature.

So the conclusion seems to be that, despite the non-applicability of the MWHC-theorem, superconductivity cannot exist in an infinite, strictly 2D system.

In real life, however, there are many examples of quasi-2D systems (even monolayers) that exhibit all the signs of superconductivity, including dissipationless current and a form of Meissner effect. The reason is that the electromagnetic field is not restricted to 2D. The field lines permeate out of the 2D layer. This causes the in-plane penetration depth $\lambda_{\rm{2D}}$ to become very large. To lowest order, one gets: $$ \lambda_{\rm{2D}} = \frac{\lambda_{\rm{L}}}{d} $$ where $\lambda_{\rm{L}}$ is the usual London penetration depth depending on the superconducting order parameter, and $d$ is the thickness of the system. For a very thin sample, the penetration depth diverges. In other words, it is a very strong type-II superconductor.

If the penetration depth becomes larger than the linear size of the system, it is effectively a neutral superfluid as far as transverse electromagnetic effects are concerned. This also implies that the vortex energy again depends logarithmically on the system size, and the BKT criterion applies. In fact, the BKT transition has been observed in many quasi-2D superconductors.

To my knowledge, none of this has been investigated really well, or at all. It would make for an interesting research project.

TL;DR The Mermin-Wagner-Hohenberg-Coleman theorem does not apply. However, due to vortex unbinding, strictly 2D superconductors would not exist. In reality, the electromagnetic field is always 3D and turns a 2D superconductor into a neutral superfluid with BKT transition.

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