Quantum Mechanics – Density Operator for the $|10\rangle$ Two Particles Spin Eigenstate

density-operatorquantum mechanicsquantum-spinsymmetry

My professor when talking about the EPR paradox said that the singlet spin state,

$$ |00\rangle=\frac{1}{\sqrt 2}(|+-\rangle-|-+\rangle) $$

is symmetric under rotation because its density matrix is

$$\rho=\frac{1}{4}(1-\vec{\sigma_1}\cdot\vec{\sigma_2}),$$

where $\vec{\sigma_1}$ and $\vec{\sigma_2}$ are the Pauli matrices for the first and second particle.

This is because for example a rotation around the $y$ axis that sends $\vec{e_z}$ to $\vec{e_x}$ and $\vec{e_x}$ to $-\vec{e_z}$, sends ${\sigma_i^z}$ to ${\sigma_i^x}$ and ${\sigma_i^x}$ to $-{\sigma_i^z}$ and so leaves $\rho$ unchanged.

But my professor said that $\rho$ for the state

$$ |10\rangle=\frac{1}{\sqrt 2}(|+-\rangle+|-+\rangle) $$

is

$$\rho=\frac{1}{2}(1+\vec{\sigma_1}\cdot\vec{\sigma_2}).$$

So also this state should be symmetric under rotations because there is a scalar product.
But this state isn't symmetric because, while the uncertainty of total spin third component $S^z$ is $0$ (the states is an eigenstate), the uncertainties of $S_x$ and $S_y$ are not $0$. This for example follows from the fact that $\langle S_x \rangle=\langle S_y \rangle=0$ and $\langle S_x^2 \rangle+\langle S_y^2 \rangle=\langle S^2 \rangle = 2\hbar$.
How to solve this contraddiction?

EDIT:

I think I figured out what happened: the $\rho$ matrix for $|10\rangle$ state can't be the one in the OP as shown in this calculation:

$$\vec{\sigma_1}\cdot\vec{\sigma_2}=
\frac{1}{2}[(\vec{\sigma_1}^2+\vec{\sigma_1})^2-\vec{\sigma_1}^2-\vec{\sigma_2}^2]=
\frac{1}{2}(\frac{2}{\hbar})^2 S_{tot}^2-3 =
\frac{2}{\hbar^2}S_{tot}^2-3$$

$$\rho=\frac{1}{\hbar^2}S_{tot}^2-1$$

$$\rho|10\rangle=|10\rangle$$
$$\rho|11\rangle=|11\rangle$$
$$\rho|1-1\rangle=|1-1\rangle$$

So $\rho$ can't be the projector onto the $|10\rangle$ state.
Can someone give me a confirmation about this?

Best Answer

My professor when talking about the EPR paradox said that the singlet spin state:

$$ |00\rangle=|+-\rangle-|-+\rangle $$

is symmetric under rotation

Yes. This is a total-spin zero ($S^2=0$) state and also has $S_z = 0$. This means it transforms trivially under rotations.

because its density matrix is

$$\rho=\frac{1}{4}(1-\vec{\sigma_1}\cdot\vec{\sigma_2})$$

...But my professor said that $\rho$ for the state: $$ |10\rangle=|+-\rangle+|-+\rangle $$

$$\rho=\frac{1}{2}(1+\vec{\sigma_1}\cdot\vec{\sigma_2})$$

So also this state should be symmetric under rotations because there is a scalar product.

No. No it should not be symmetric. The state you wrote above is the $S_z=0$ part of the triplet. It transforms like a vector component into the other components of the triplet.

But this state isn't symmetric...

Yes. The components of the triplet do transform under rotations.

How to solve this contraddiction? [sic]

There is no contradiction. Also, as discussed below, one of the expressions for one of the density matrices you wrote above is incorrect.


Update:

I think I figured out what happened: the $\rho$ matrix for $|10\rangle$ state can't be the one in the OP as shown in this calculation:

Yes. I agree. The density matrix for $|10\rangle$ is: $$ |10\rangle\langle 10| \propto \left( \begin{matrix} 0 & 0 & 0 & 0 \\ 0 & 1 & 1 & 0 \\ 0 & 1 & 1 & 0 \\ 0 & 0 & 0 & 0 \end{matrix} \right) $$ whereas the expression $1 + \vec{\sigma_1}\cdot\vec{\sigma_2}$ is: $$ 1 + \vec{\sigma_1}\cdot\vec{\sigma_2} \propto \left( \begin{matrix} 1 & 0 & 0 & 0 \\ 0 & 0 & 1 & 0 \\ 0 & 1 & 0 & 0 \\ 0 & 0 & 0 & 1 \end{matrix} \right)\;, $$ so they are not the same.

However, the expression for $|00\rangle\langle 00| = \frac{1}{4}\left(1 - \sigma_1\cdot\sigma_2\right)$ is fine.

So $\rho$ can't be the projector onto the $|10\rangle$ state. Can someone give me a confirmation about this?

I can confirm in the sense provided in the update above.

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