I am having trouble differentiating between the two.
If we have a Hilbert space $H$, which has an ortho-normal basis ${|n\rangle}$. Then is it right to say that ${|n\rangle}$ are the eigenvectors of the Hilbert space, belonging to some eigenvalues?
Do we find the eigenvalues by having an hermitian operator A act on the eigenvectors: $A|n\rangle = b |n\rangle$.
But if we have $|\Psi\rangle =\Sigma_n c_n|n\rangle$ as a linear superposition of the eigenvectors of the Hilbert space, then we can do the following:
$A|\Psi\rangle=k |\Psi\rangle $ where: $k$ is the eigenvalue of the hermitian operator, represented by a matrix and $|\Psi\rangle$ is the eigenvector of the eigenvalue $k$.
Does the hermitian operator $A$ and the Hilbert space $H$, each have their own eigenvalues and vectors?
Best Answer
Eigenvectors and eigenvalues are properties of operators, not of Hilbert spaces. Hence, answering the first part of your question, if $| n \rangle$ is an orthonormal basis of $\mathcal{H}$ (the Hilbert space), it is not correct to say they are the eigenvalues of the Hilbert space. We simply say they are an orthonormal basis.
Suppose now you are given an operator $A \colon \mathcal{H} \to \mathcal{H}$ on the Hilbert space. Loosely speaking, a matrix. A vector $| \Psi \rangle \in \mathcal{H}$ is said to be an eigenvector of $A$ associated to the eigenvalue $a$ when $A | \Psi \rangle = a | \Psi \rangle$. Notice that I need the operator to define what I mean by eigenvector: eigenvectors are the vectors in which $A$ acts as if it was simply a number, this number being called an eigenvalue.
Now if $A$ is hermitian, there are two cool results:
Hence, if you are given a hermitian operator on the Hilbert space, you can use it to obtain a basis. We usually pick the Hamiltonian, for example, because then each state in the basis has a simple time-evolution in terms of its energy (more specifically, in terms of the eigenvalue of the Hamiltonian to which it is associated). By the very definition of what a basis is, we can then write any vector in the Hilbert space in terms of eigenvectors of the Hamiltonian, i.e., in terms of states of definite energy. This provides a nice way to write down the time evolution of the state, since the Hamiltonian eigenstates have simple time-evolution rules.
We could pick other operators, if we so desired. Instead of the Hamiltonian, you could pick some other hermitian operator to obtain a basis, but it would probably be less convenient to work with.
Finally, it is worth mentioning that sometimes a few linearly independent states might be associated to the same eigenvalue. We call this degeneracy. In this case, we often need a few more operators (such as angular momentum squared and angular momentum in the $\vec{z}$ direction) to properly label all the states in the basis in a unique way. This is what happens when we solve for the hydrogen atom and need three labels to define uniquely which state in the basis is which, because a few of them have the same energy (as a consequence, we distinguish them by using their angular momentum properties).