The code of "xlswrite.m" contains the following text:
DEC2BASE27(D) returns the representation of D as a string in base 27, expressed as 'A'..'Z', 'AA','AB'...'AZ', until 'IV'. Note, there is no zero digit, so strictly we have hybrid base26, base27 number system. D must be a negative integer bigger than 0 and smaller than 2^52, which is the maximum number of columns in an Excel worksheet.
2^52 is not a typographical error because two more statements quote the
same value. I believe the the maximum number of columns in Excel is 256.
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