No, not a hope.
mexw32 files and mexw64 files are MS Windows .dll files with a different file extension (and particular routines expected to exist in them.) It is MS Windows itself that is not able to use a 32 bit DLL from inside a 64 bit program.
(This is such a common restriction in operating systems that I have never encountered an operating system that permitted 32 bit shared libraries to be called from 64 bit programs. The closest I have ever seen was that 32 bit MC68000-based programs call call upon 16 bit Z80 operating system calls in Cromemco Cromix computers in the early 1980s; that was handled by using a shared memory segment in way that would not be acceptable in any modern computer architecture.)
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