There are a lot of tools for this job in the FEX, e.g.WindowAPI. This tool can use the Windows HWnd handle as input, such that I expect it to work on not-Matlab windows also - as long as you find a method to get the HWnd...
Did you click the star tag link on the right? If you had, you would have come up with plenty of hits, such as this one where I gave code to draw a star:
Carlos - do you mean that you wish your GUI (created in GUIDE) should always be above any other window (figure, other GUI, etc.)?
Consider usinguistack to control the visual stacking order of the objects. It may mean that every new figure that you create (from your GUI?) would have to have a lower order relative to the GUI.
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