MATLAB: How to fit the equation with that curve..?? please help..!!!

curve plotequationplot fittingpolynominal

Here's my equation
and the plot
I have to Fit this equation with the given plot and find the value of parameters Vo, Ro, ao, V1, D1 and R1. Please someone help me.. I have attached a pdf file of my problem.
Here's a lot of data..

R-----------V(R)
0.0000 -373.7902
0.0500 -373.7437
0.1000 -373.6783
0.1500 -373.5867
0.2000 -373.4592
0.2500 -373.2830
0.3000 -373.0417
0.3500 -372.7141
0.4000 -372.2737
0.4500 -371.6875
0.5000 -370.9155
0.5500 -369.9093
0.6000 -368.6124
0.6500 -366.9592
0.7000 -364.8755
0.7500 -362.2792
0.8000 -359.0819
0.8500 -355.1907
0.9000 -350.5117
0.9500 -344.9538
1.0000 -338.4338
1.0500 -330.8817
1.1000 -322.2471
1.1500 -312.5056
1.2000 -301.6648
1.2500 -289.7705
1.3000 -276.9108
1.3500 -263.2197
1.4000 -248.8777
1.4500 -234.1107
1.5000 -219.1859
1.5500 -204.4052
1.6000 -190.0958
1.6500 -176.5985
1.7000 -164.2542
1.7500 -153.3897
1.8000 -144.3026
1.8500 -137.2475
1.9000 -132.4235
1.9500 -129.9640
2.0000 -129.9300
2.0500 -132.3065
2.1000 -137.0031
2.1500 -143.8585
2.2000 -152.6480
2.2500 -163.0943
2.3000 -174.8807
2.3500 -187.6647
2.4000 -201.0935
2.4500 -214.8176
2.5000 -228.5041
2.5500 -241.8472
2.6000 -254.5773
2.6500 -266.4667
2.7000 -277.3327
2.7500 -287.0382
2.8000 -295.4905
2.8500 -302.6369
2.9000 -308.4606
2.9500 -312.9743
3.0000 -316.2143
3.0500 -318.2342
3.1000 -319.0989
3.1500 -318.8797
3.2000 -317.6501
3.2500 -315.4821
3.3000 -312.4442
3.3500 -308.5996
3.4000 -304.0061
3.4500 -298.7159
3.5000 -292.7760
3.5500 -286.2300
3.6000 -279.1186
3.6500 -271.4815
3.7000 -263.3587
3.7500 -254.7919
3.8000 -245.8250
3.8500 -236.5055
3.9000 -226.8845
3.9500 -217.0168
4.0000 -206.9606
4.0500 -196.7768
4.1000 -186.5282
4.1500 -176.2782
4.2000 -166.0896
4.2500 -156.0234
4.3000 -146.1371
4.3500 -136.4843
4.4000 -127.1128
4.4500 -118.0646
4.5000 -109.3748
4.5500 -101.0719
4.6000 -93.1772
4.6500 -85.7055
4.7000 -78.6650
4.7500 -72.0582
4.8000 -65.8825
4.8500 -60.1306
4.9000 -54.7916
4.9500 -49.8513
5.0000 -45.2933
5.0500 -41.0991
5.1000 -37.2493
5.1500 -33.7236
5.2000 -30.5013
5.2500 -27.5620
5.3000 -24.8854
5.3500 -22.4519
5.4000 -20.2426
5.4500 -18.2394
5.5000 -16.4252
5.5500 -14.7840
5.6000 -13.3006
5.6500 -11.9612
5.7000 -10.7526
5.7500 -9.6628
5.8000 -8.6809
5.8500 -7.7966
5.9000 -7.0007
5.9500 -6.2846
6.0000 -5.6407
6.0500 -5.0618
6.1000 -4.5416
6.1500 -4.0742
6.2000 -3.6545
6.2500 -3.2776
6.3000 -2.9393
6.3500 -2.6357
6.4000 -2.3632
6.4500 -2.1188
6.5000 -1.8995
6.5500 -1.7027
6.6000 -1.5263
6.6500 -1.3681
6.7000 -1.2262
6.7500 -1.0991
6.8000 -0.9850
6.8500 -0.8828
6.9000 -0.7911
6.9500 -0.7090
7.0000 -0.6354
7.0500 -0.5694
7.1000 -0.5102
7.1500 -0.4572
7.2000 -0.4097
7.2500 -0.3671
7.3000 -0.3289
7.3500 -0.2947
7.4000 -0.2641
7.4500 -0.2366
7.5000 -0.2120
7.5500 -0.1900
7.6000 -0.1702
7.6500 -0.1525
7.7000 -0.1367
7.7500 -0.1225
7.8000 -0.1097
7.8500 -0.0983
7.9000 -0.0881
7.9500 -0.0789
8.0000 -0.0707
8.0500 -0.0634
8.1000 -0.0568
8.1500 -0.0509
8.2000 -0.0456
8.2500 -0.0408
8.3000 -0.0366
8.3500 -0.0328
8.4000 -0.0294
8.4500 -0.0263
8.5000 -0.0236
8.5500 -0.0211
8.6000 -0.0189
8.6500 -0.0170
8.7000 -0.0152
8.7500 -0.0136
8.8000 -0.0122
8.8500 -0.0109
8.9000 -9.7904e-3
8.9500 -8.7719e-3
9.0000 -7.8593e-3
9.0500 -7.0417e-3
9.1000 -6.3091e-3
9.1500 -5.6528e-3
9.2000 -5.0647e-3
9.2500 -4.5378e-3
9.3000 -4.0657e-3
9.3500 -3.6427e-3
9.4000 -3.2638e-3
9.4500 -2.9242e-3
9.5000 -2.6200e-3
9.5500 -2.3474e-3
9.6000 -2.1032e-3
9.6500 -1.8844e-3
9.7000 -1.6884e-3
9.7500 -1.5127e-3
9.8000 -1.3553e-3
9.8500 -1.2143e-3
9.9000 -1.0880e-3
9.9500 -974.82e-6
10.0000 -873.40e-6
10.0500 -782.54e-6
10.1000 -701.13e-6
10.1500 -628.19e-6
10.2000 -562.83e-6
10.2500 -504.28e-6
10.3000 -451.82e-6
10.3500 -404.81e-6
10.4000 -362.70e-6
10.4500 -324.96e-6
10.5000 -291.16e-6
10.5500 -260.87e-6
10.6000 -233.73e-6
10.6500 -209.41e-6
10.7000 -187.62e-6
10.7500 -168.11e-6
10.8000 -150.62e-6
10.8500 -134.95e-6
10.9000 -120.91e-6
10.9500 -108.33e-6
11.0000 -97.059e-6
11.0500 -86.962e-6
11.1000 -77.915e-6
11.1500 -69.809e-6
11.2000 -62.546e-6
11.2500 -56.039e-6
11.3000 -50.209e-6

Best Answer

using cftool:
General model:
f(R) = -V0/(1+exp((R-R0)/a0)) + V1*exp(-((R-D1)/R1)^2)
Coefficients (with 95% confidence bounds):
D1 = -0.06323
R0 = -0.07497
R1 = -4.55 (-5.504, -3.596)
V0 = -12.93 (-26.51, 0.6514)
V1 = -350.6 (-392.5, -308.6)
a0 = -0.00316 (-1.442e+07, 1.442e+07)
And the graph looks pretty bad.
Notice that the confidence interval for V0 crosses 0, so it is having trouble figuring out whether the first term should be added or subtracted. This almost always implies that the fit is nonsense.
Notice too that a0 is large and both positive and negative. a0 is a divisor in exp(), so a large positive or negative divisor implies that the fit is trying to drive the effect of the exp term to 0, effectively making the first term with V0 into a linear term instead of an exponential: that might lead to a better fit mathematically, but clearly it would lead to a plot with only one hump.