The fwhm function is a File Exchange contribution. As I read the function code, it should likely give you something other than NaN if it detects 2 edges, however I have no idea what youare passing to it.
If you have the Signal Processing Toolbox, another option would be the findpeaks function. It will return the FWHM of the peaks it identifies if you ask it to. See the documentation for it that I linked to for details.
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