What do you expect? It seems you keep on doing these computations, but then fail to think about the result, not thinking why you get what you did. For example...
corrcoef(Absorbance1, Absorbance2)
ans =
1 0.999999780102625
0.999999780102625 1
The coreelation coefficient is NOT 1. However, it is very near 1. Not exactly so though.
p1 = polyfit(Absorbance1',Absorbance2',1)
p1 =
2.50345381465648 -0.0079603101543761
[Absorbance1'*p1(1) + p1(2), Absorbance2']
ans =
0.00319199569957401 0.00396857486191138
0.580997733409916 0.580941962999683
1.15897081349257 1.15836071715381
1.73713188545425 1.73637553044848
2.31550417871278 2.31518905653607
2.89411383324176 2.8950745980109
So, if we transform Absorbance1 by a linear transformation, we get something virtually identical to Absorbance2.
Likewise, C is a perfectly linear sequence.
C
C =
0 10 20 30 40 50
diff(Absorbance1)
ans =
0.230803434170655 0.230870278772036 0.230945371780708 0.231029743737411 0.231124557258262
As you should see by the differences there, Absorbance1 is nearly so too.
Can you possibly expect to not see nearly unit correlations for each of those comparisons? Two perfectly linear (non-constant) sequences will have a correlation coefficient that is either 1 or -1.
Look at what you get. Don't just compute a number and assume it has any meaning. Think about what you have done. Does what you did make sense?
Best Answer