In OS-X, because applications launched from the dock do not go through a login shell, the full shell initialization files are not used, so the PATH environment variable will probably not be the same.
You can either use the full path to R or you can setenv('PATH') to include the path to R, or you can alter the OS-X environment variables.
You might be able to modify /etc/paths but I am not sure that works in newer versions.
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